479421-97-1

Basic information

• Product Name: Benzoic acid, 4-(ethenylsulfonyl)-, methyl ester
• CAS NO: 479421-97-1
• Molecular Formula: C10H10O4S
• Molecular Weight: 226.253
• Mol File: 479421-97-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 4-(ethenylsulfonyl)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 4-(ethenylsulfonyl)-, methyl ester(479421-97-1)
• EPA Substance Registry System: Benzoic acid, 4-(ethenylsulfonyl)-, methyl ester(479421-97-1)

Safety Data

• Hazardous Substances Data: 479421-97-1(Hazardous Substances Data)

Upstream product

• 69812-51-7 4-chlorosulfonyl-benzoic acid methyl ester 
• 106-93-4 ethylene dibromide 
• 6302-65-4 methyl 4-mercaptobenzoate 
• 872674-88-9 methyl 4-[(2-bromoethyl)sulfonyl]benzoate 
• 14184-32-8 4-(2-bromoethylsulfanyl)benzoic acid methyl ester 

Downstream Products

• 872674-91-4 methyl 4-[[2-(7-chloro-2-methyl-1H-indol-3-yl)ethyl]sulfonyl]benzoate 
• 872674-93-6 methyl 4-[[2-(4,5-dichloro-2-methyl-1H-indol-3-yl)ethyl]sulfonyl]benzoate 
• 872674-92-5 methyl 4-[[2-(5,6-dichloro-2-methyl-1H-indol-3-yl)ethyl]sulfonyl]benzoate 
• 872675-00-8 methyl 4-[[2-[4,5-dichloro-(1-diphenylmethyl)-2-methyl-1H-indol-3-yl]ethyl]sulfonyl]benzoate 
• 872674-99-2 methyl 4-[[2-[5,6-dichloro-(1-diphenylmethyl)-2-methyl-1H-indol-3-yl]ethyl]sulfonyl]benzoate 
• 872674-97-0 methyl 4-[[2-[7-chloro-(1-diphenylmethyl)-2-methyl-1H-indol-3-yl]ethyl]sulfonyl]benzoate 
• 872674-95-8 methyl 4-[[2-[4-chloro-(1-diphenylmethyl)-2-methyl-1H-indol-3-yl]ethyl]sulfonyl]benzoate 
• 872674-94-7 methyl 4-[[2-[6-chloro-(1-diphenylmethyl)-2-methyl-1H-indol-3-yl]ethyl]sulfonyl]benzoate 
• 872675-01-9 methyl 4-[[2-[1-(diphenylmethyl)-5-fluoro-2-methyl-1H-indol-3-yl]ethyl]sulfonyl]benzoate 
• 479422-09-8 methyl 4-[[2-[1-(diphenylmethyl)-5-methoxy-2-methyl-1H-indol-3-yl]ethyl]sulfonyl]benzoate 
• 479422-06-5 methyl 4-[[2-[1-(diphenylmethyl)-2-methyl-1H-indol-3-yl]ethyl]sulfonyl]benzoate 
• 479422-08-7 methyl 4-[[2-(5-methoxy-2-methyl-1H-indol-3-yl)ethyl]sulfonyl]benzoate 
• 479421-98-2 methyl 4-[[2-(5-fluoro-2-methyl-1H-indol-3-yl)ethyl]sulfonyl]benzoate 
• 479422-05-4 methyl 4-[[2-(2-methyl-1H-indol-3-yl)ethyl]sulfonyl]benzoate 

Relevant articles and documents

Diastereoselective Monofluorocyclopropanation Using Fluoromethylsulfonium Salts

Diarylfluoromethylsulfonium salts, alternatives to freons or advanced fluorinated building blocks, are bench stable and easy-to-use sources of direct fluoromethylene (:CHF) transfer to alkenes. These salts enabled development of a trans-selective monofluorinated Johnson-Corey-Chaykovsky reaction with vinyl sulfones or vinyl sulfonamides to access synthetically challenging monofluorocyclopropane scaffolds. The described method offers rapid access to monofluorinated cyclopropane building blocks with further functionalization opportunities to deliver more complex synthetic targets diastereoselectively.