2602-61-1

Basic information

• Product Name: N,N-Diethyldecanamide
• Synonyms: N,N-DIETHYLDECANAMIDE
• CAS NO: 2602-61-1
• Molecular Formula: C₁₄H₂₉NO
• Molecular Weight: 227.39
• Mol File: 2602-61-1.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 284.9 °C at 760 mmHg
• Flash Point: 106 °C
• Appearance: colorless transparent liquid
• Density: 0.861 g/cm³
• Vapor Pressure: 0.00289mmHg at 25°C
• Refractive Index: 1.447
• Storage Temp.: 2-8°C
• PKA: -0.42±0.70(Predicted)
• CAS DataBase Reference: N,N-Diethyldecanamide(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-Diethyldecanamide(2602-61-1)
• EPA Substance Registry System: N,N-Diethyldecanamide(2602-61-1)

Safety Data

• Hazardous Substances Data: 2602-61-1(Hazardous Substances Data)

Usage

General Description

N,N-Diethyldecanamide is a chemical compound with the molecular formula C16H33NO. It is commonly used as an insect repellent and is found in a variety of commercial insect repellent products. Due to its chemical structure, N,N-Diethyldecanamide is effective at repelling a wide range of insects including mosquitoes, ticks, and fleas. It works by interfering with the insect's ability to detect and locate potential hosts, making it a popular choice for outdoor activities and in areas where insect-borne diseases are prevalent. N,N-Diethyldecanamide is considered to be a safe and effective insect repellent and is approved for use by regulatory agencies such as the Environmental Protection Agency (EPA) in the United States.

InChI:InChI=1/C14H29NO/c1-4-7-8-9-10-11-12-13-14(16)15(5-2)6-3/h4-13H2,1-3H3

Upstream product

• 706-14-9 5-hexyldihydro-2(3H)-furanone 
• 109-89-7 diethylamine 
• 693-04-9 butyl magnesium bromide 
• 150514-56-0 N,N-diethyl-6-bromohexanamide 
• 660-68-4 diethyl amine hydrochloride 
• 112-13-0 n-decanoyl chloride 
• 334-48-5 1-decanoic acid 
• 111-66-0 oct-1-ene 
• 2430-01-5 2-bromo-N,N-diethylacetamide 

Downstream Products

• 112-30-1 1-Decanol 
• 112-31-2 caprinaldehyde 
• 6308-94-7 n-decyldiethylamine 

Relevant articles and documents

Iridium-Catalyzed Reductive Strecker Reaction for Late-Stage Amide and Lactam Cyanation

A new iridium-catalyzed reductive Strecker reaction for the direct and efficient formation of α-amino nitrile products from a broad range of (hetero)aromatic and aliphatic tertiary amides, and N-alkyl lactams is reported. The protocol exploits the mild and highly chemoselective reduction of the amide and lactam functionalities using IrCl(CO)[P(C6H5)3]2 (Vaska's complex) in the presence of tetramethyldisiloxane, as a reductant, to directly generate hemiaminal species able to undergo substitution by cyanide upon treatment with TMSCN (TMS=trimethylsilyl). The protocol is simple to perform, broad in scope, efficient (up to 99 % yield), and has been successfully applied to the late-stage functionalization of amide- and lactam-containing drugs, and naturally occurring alkaloids, as well as for the selective cyanation of the carbonyl carbon atom linked to the N atom of proline residues within di- and tripeptides.

Nickel-catalyzed cross-coupling of unactivated alkyl halides and tosylate carrying a functional group with alkyl and phenyl Grignard reagents

By the use of catalytic amounts of a nickel salt and a 1,3-butadiene, primary and secondary alkyl Grignard reagents undergo cross-coupling with alkyl bromides, iodide, and tosylate carrying a functional group such as amide, ester, and ketone at 0 °C in THF. The present procedure provides a simple, convenient, and practical method for construction of carbon chains in the presence of various functional groups. PhMgBr also gave the corresponding coupling product in a moderate yield.

Facile Homologation of N,N-Dialkyl-α-bromoacetamide by Trialkylboranes in the Presence of Lithium Diisopropylamide

-