13341-72-5 Usage
Description
FEMA 3764, also known as Menthalactone, is a naturally occurring compound found in mint, specifically in peppermint and pennyroyal oil, Mentha arvensi. It has a creamy, coconut, coumarin, milky lactonic taste with a slight minty and anisic nuance at 20 ppm, and a sweet, creamy coumarinic, slightly powdery coconut, brown vanilla-like, and slightly bread-like aroma at 10.0% concentration.
Uses
Used in Flavor and Fragrance Industry:
FEMA 3764 is used as a flavoring agent for its creamy, coconut, and coumarin-like taste characteristics, adding a unique flavor profile to food and beverage products.
FEMA 3764 is also used as a fragrance ingredient for its sweet, creamy, and slightly powdery coconut aroma, contributing to the overall scent of personal care and cosmetic products.
Used in Pharmaceutical Industry:
Menthalactone, as a component of mint, may contribute to its analgesic activity. Therefore, FEMA 3764 can be used in the development of pain-relief medications and topical analgesic formulations.
Preparation
By asymmetric dihydroxylation reaction from intrinsically disflavored diastereoface of alkene
Synthesis Reference(s)
Tetrahedron Letters, 31, p. 6789, 1990 DOI: 10.1016/S0040-4039(00)97172-7
Biochem/physiol Actions
Taste at 20 ppm
Check Digit Verification of cas no
The CAS Registry Mumber 13341-72-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,3,4 and 1 respectively; the second part has 2 digits, 7 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 13341-72:
(7*1)+(6*3)+(5*3)+(4*4)+(3*1)+(2*7)+(1*2)=75
75 % 10 = 5
So 13341-72-5 is a valid CAS Registry Number.
InChI:InChI=1/C10H14O2/c1-6-3-4-8-7(2)10(11)12-9(8)5-6/h6,9H,3-5H2,1-2H3/t6-,9-/m1/s1
13341-72-5Relevant articles and documents
Regio- and stereoselective selenium dioxide allylic oxidation of (E)-dialkyl alkylidenesuccinates to (Z)-allylic alcohols: Synthesis of natural and unnatural butenolides
Patel, Ramesh M.,Puranik, Vedavati G.,Argade, Narshinha P.
, p. 6312 - 6322 (2011/10/09)
The first SeO2 induced (Z)-selective allylic alcohol formation of dialkyl alkylidenesuccinates has been demonstrated to accomplish one-step syntheses of several essential butenolides and fused butenolides via an unusual E- to Z- carbon-carbon d
Reaction of β,γ-unsaturated carboxylic acids with Thallium triacetate (TTA): Lactonization vs oxidative decarboxylation
Ferraz,Grazini,Silva L.F.,Longo L.S.
, p. 1953 - 1964 (2007/10/03)
The reaction of six β,γ-unsaturated carboxylic acids with thallium triacetate (TTA) was studied. The nature of the products is highly sensitive to the substitution pattern of the substrates. Aliphatic acids gave mainly lactones, while those bearing an aro
An Efficient Entry Into Butenolides: Synthesis Of (+/-) Mintlactone
Chavan, Subhash P.,Zubaidha, P. K.,Ayyangar, Nagaraj R.
, p. 4605 - 4608 (2007/10/02)
Osmylation of β,γ-unsaturated esters and acid catalysed cyclisation of the resultant diols generate butenolides in high yields.
