127469-78-7Relevant articles and documents
BIS(N,N-DIETHYLCARBAMATO)BIS(DIETHYLAMINE)PALLADIUM(II), THE FIRST HOMOLEPTIC CARBAMATO COMPLEX OF PALLADIUM
Anillo, Adela,Dell'Amico, Daniela Belli,Calderazzo, Fausto,Pelizzi, Giancarlo,Rocchi, Lucia
, p. 653 - 656 (2007/10/02)
The reaction of NHEt2 and carbon dioxide with (BF4)2 at room temperature and atmospheric pressure produced the N-N-diethylcarbamato complex trans-Pd(O2CNEt2)2(NHEt2)2.Single-crystal X-ray diffractometry showed the monodentate carbamato groups and the amine ligands in a planar arrangement of the donor atoms around palladium.Evidence for the formation of the corresponding isopropyl derivative is presented.