1138991-50-0

Basic information

• Product Name: [Ru(2-mercapto-5-methyl-1,3,4-thiadiazole(-H))(1,1'-bis(diphenylphosphanyl)ferrocene)(η5-indenyl)]
• CAS NO: 1138991-50-0
• Molecular Weight: 901.818
• Mol File: 1138991-50-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Ru(2-mercapto-5-methyl-1,3,4-thiadiazole(-H))(1,1'-bis(diphenylphosphanyl)ferrocene)(η5-indenyl)](CAS DataBase Reference)
• NIST Chemistry Reference: [Ru(2-mercapto-5-methyl-1,3,4-thiadiazole(-H))(1,1'-bis(diphenylphosphanyl)ferrocene)(η5-indenyl)](1138991-50-0)
• EPA Substance Registry System: [Ru(2-mercapto-5-methyl-1,3,4-thiadiazole(-H))(1,1'-bis(diphenylphosphanyl)ferrocene)(η5-indenyl)](1138991-50-0)

Safety Data

• Hazardous Substances Data: 1138991-50-0(Hazardous Substances Data)

Upstream product

• 910581-94-1 (η5-indenyl)(1,1'-bis(diphenylphosphanyl)ferrocene)ruthenium(II) chloride 
• 29490-19-5 2-methyl-1,3,4-thiadiazoline-5-thione 

Relevant articles and documents

Synthesis, X-ray crystal structures and electrochemistry of (indenyl)-ruthenium complexes containing dppf and heterocyclic thiolato/thione ligands

A number of (indenyl)ruthenium complexes containing dppf [1,1′-bis(diphenylphosphanyl)ferrocene] and heterocyclic thiolato/thione ligands have been synthesized. All the complexes were fully characterized by microanalytical and spectroscopic techniques, together with X-ray diffraction analyses for those containing the benzothiazolato (thiolato) and the thiadiazole (thione) ligands. Cyclic voltammetry (CV) experiments indicated that these complexes can be oxidized in three one-electron processes at positive potentials. Differences in chemical reversibility observed during variable-temperature CV experiments indicated that it was likely that the oxidation processes occurred at two electronically non-communicating sites within the molecules. One site could be assigned as the oxidation of the Ru ion (two one-electron processes), whilst the second site was assigned as the oxidation of the dppf (one one-electron process). Wiley-VCH Verlag GmbH & Co. KGaA, 2008.