101965-93-9

Basic information

• Product Name: H₃B(PPh₂(C₆H₄CH₃))
• Synonyms: H₃B(PPh₂(C₆H₄CH₃))
• CAS NO: 101965-93-9
• Molecular Weight: 290.153
• Mol File: 101965-93-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: H₃B(PPh₂(C₆H₄CH₃))(CAS DataBase Reference)
• NIST Chemistry Reference: H₃B(PPh₂(C₆H₄CH₃))(101965-93-9)
• EPA Substance Registry System: H₃B(PPh₂(C₆H₄CH₃))(101965-93-9)

Safety Data

• Hazardous Substances Data: 101965-93-9(Hazardous Substances Data)

Upstream product

• 1031-93-2 diphenyl(p-tolyl)phosphine 
• 624-31-7 4-tolyl iodide 
• 41593-58-2 diphenylphosphineborane 

Downstream Products

• 1031-93-2 diphenyl(p-tolyl)phosphine 

Relevant articles and documents

Phosphine-Borane complexes: In situ deprotection and application as ligands in the Rh- or Pd-Catalysed hydroformylation reaction

Triarylphosphine-borane complexes are directly useful in the Rh-catalysed hydroformylation reaction of 1-octene (or Pdcatalysed hydroformylation of 1-pentene). Mild reaction conditions provide similar yields and selectivities of the anticipated aldehyde products to reactions making use of the corresponding free phosphines as ligands. The mono- or bidentate P-B adducts undergo in situ CO-mediated deprotection the produce the free phosphine ligands. The results demonstrate that phosphine-borane complexes may be directly applied to carbonylation reactions without a prior deprotection step, with little to no change in the reaction outcome.