10170-27-1

Basic information

• Product Name: hexacarbonyl-bis-(triphenylphosphine) dicobalt
• CAS NO: 10170-27-1
• Molecular Weight: 810.631
• Mol File: 10170-27-1.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: hexacarbonyl-bis-(triphenylphosphine) dicobalt(CAS DataBase Reference)
• NIST Chemistry Reference: hexacarbonyl-bis-(triphenylphosphine) dicobalt(10170-27-1)
• EPA Substance Registry System: hexacarbonyl-bis-(triphenylphosphine) dicobalt(10170-27-1)

Safety Data

• Hazardous Substances Data: 10170-27-1(Hazardous Substances Data)

Upstream product

• 53433-12-8 [bis(triphenylphospine)nitrogen⁽¹⁺⁾][Co(CO)4] 
• 83605-43-0 N,N'-dimethyl-[2,2'-bipyridine]-1,1'-diium hexafluorophosphate 
• 21373-88-6 (PPh₃)3CoH(N₂) 
• 17125-96-1 CoH₃(PPh₃)3 
• 15041-50-6 tetracobaltdodecacarbonyl 
• 15226-74-1 dicobalt octacarbonyl 
• 603-35-0 triphenylphosphine 
• 14243-08-4 tricarbonyldi(triphenylphosphine)cobalt⁽¹⁺⁾ tetracarbonylcobaltate^(1-) 
• 22992-02-5 HCo(NCCH₃)(P(C₆H₅)3)3 
• 13557-43-2 1,2-bis(pentafluorophenyl)acetylene 
• 929-87-3 cobalt(II) stearate 
• 15226-74-1 dicobalt octacarbonyl 
• 17787-17-6 Co(CO)3(P(C₆H₅)3)2⁽¹⁺⁾*PF₆^(1-)=(Co(CO)3(P(C₆H₅)3)2)PF₆ 
• 201230-82-2 carbon monoxide 

Downstream Products

• 33570-17-1 sodium tricarbonyl(triphenylphosphino)cobaltate 
• 86885-13-4 {Co(CO)3P(C₆H₅)3}2GeF₂ 
• 15747-05-4 trans-Cl₂Sn(Co(CO)3PPh₃)2 
• 10170-27-1 Co₂(CO)6(PPh₃)2 
• 36158-67-5 CoI(CO)3(P(C₆H₅)3) 
• 95420-10-3 trans-tricarbonyl(triphenylphosphine){spirobi(1,3,2-benzodioxaphosphol-2-yl)}cobalt * diethyl ether 
• 36869-22-4 Co((CH₃)3Sn)(CO)3P(C₆H₅)3 
• 136354-91-1 dicarbonyl{η2-diphenyl(phenylphosphandiyl)phosphinito}triphenylphosphane cobalt 
• 33700-29-7 Cs⁽¹⁺⁾*{Co(CO)3P(C₆H₅)3}^(1-)=Cs{Co(CO)3P(C₆H₅)3} 
• 136386-90-8 (butyldiphenylphosphane)dicarbonyl{η2-(cyclohexylphosphandiyl)diphenylphosphinito} cobalt 
• 136355-22-1 dicarbonyl{η2-diphenyl(cyclohexylphosphandiyl)phosphinito}triphenylphosphane cobalt 
• 136386-89-5 dicarbonyldiphenylphosphane{η2-diphenyl(t-butylphosphandiyl)phosphinito}cobalt 
• 136355-21-0 dicarbonyl{η2-diphenyl(t-butylphosphandiyl)phosphinito}triphenylphosphane cobalt 
• 136355-20-9 dicarbonyl{η2-diphenyl(2,4,6-tri-t-butylphenylphosphandiyl)phosphinito}triphenylphosphane cobalt 

Relevant articles and documents

Stable catalyst for intermolecular Pauson-Khand reaction

The catalytic activity of previously formed Co2(CO) 6[P(Ph)3]2 (1) was compared with Co 2(CO)8 and the system formed by Co2(CO) 8 plus PPh3 in the intermole

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Structural studies of derivatives of methinyltricobalt enneacarbonyls. III. Crystal structure and reaction studies of bis(methinyltricobalt enneacarbonyl)acetylene (Co6(CO)18C4)

The compound Co6(CO)18C4 is one product of the reaction of ClCCo3(CO)9 with mesitylene. Its crystal and molecular structure has been determined by three-dimensional X-ray analysis. Crystals are triclinic, space group P1 with one centrosymmetric molecule in a cell of dimensions a = 8.87 (1), b = 12.61 (2), c = 7.97 (1) ?; α = 106.9 (2), β = 111.7 (1), γ = 70.1 (1)°. X-Ray data were collected by conventional film techniques using Co Kα radiation and the intensities of 1088 reflections above background were measured photometrically. The structure was refined anisotropically by full-matrix least-squares procedures to a conventional R factor of 0.047. The structure is composed of discrete molecules formed by the insertion of a carbon-carbon triple bond between two identical -CCo3(CO)9 units. In the linear carbon chain, C-C≡C-C, at the center of the molecule, the C-C and C≡C bond lengths are 1.37 (1) and 1.24 (2) ?, respectively. The mean Co-Co bond length is 2.47 (1) ?. The optimum experimental conditions for formation of Co6(CO)18C4 and related compounds from arenes and YCo3(CO)9 compounds are given and a number of reactions of Co6(CO)18C4 and derivatives are reported and discussed.

An NMR study of cobalt-catalyzed hydroformylation using para-hydrogen induced polarisation

The syntheses of Co(η3-C3H5)(CO) 2PR2R′ (R, R′ = Ph, Me; R, R′ = Me, Ph; R = R′ = Ph, Cy, CH2Ph) and Co(η3-C 3H5)(CO)(L) (L = dmpe and dppe) are described,

Ion-Pair Charge Transfer (IPCT) between bipyridinium cations and the tetracarbonylcobaltate anion. Spectroscopy and thermal and photochemical reactions

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