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CAS No.: | 92867-55-5 |
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Name: | Propane, 1,2,3-tris(1,1-dimethylethoxy)- |
Article Data: | 21 |
Molecular Structure: | |
Formula: | C15H32O3 |
Molecular Weight: | 260.417 |
Synonyms: | 1,2,3-tri-tert-butoxypropane;tri-tert-butyl-glycerol;1.2.3-Tri-tert-butoxypropan;tri-tert-butyl glycerol ether;glycerol tri-tert-butyl ether; |
PSA: | 27.69000 |
LogP: | 3.80030 |
glycerol
isobutene
A
1,2-di-tert-butylglycerol ether
B
3-(tert-butoxy)propane-1,2-diol
C
1,3-di-tert-buthyl glycerol ether
D
tri-tert-butyl glycerol ether
Conditions | Yield |
---|---|
With A35 resin acid at 75℃; under 11251.1 Torr; for 20h; Inert atmosphere; | A n/a B n/a C 80% D n/a |
glycerol
tert-butyl alcohol
A
1,2-di-tert-butylglycerol ether
B
3-(tert-butoxy)propane-1,2-diol
C
1,3-di-tert-buthyl glycerol ether
D
tri-tert-butyl glycerol ether
Conditions | Yield |
---|---|
With 1-methyl-imidazolium p-toluenesulfonic acid at 100℃; under 11251.1 Torr; for 24h; Inert atmosphere; | A n/a B n/a C 65% D n/a |
With unilamellar MFI zeolite nanosheet at 119.84℃; for 12h; Reagent/catalyst; Autoclave; |
glycerol
tert-butyl alcohol
A
3-(tert-butoxy)propane-1,2-diol
B
1,3-di-tert-buthyl glycerol ether
C
tri-tert-butyl glycerol ether
Conditions | Yield |
---|---|
With pillared clay treatedwith fuming sulfuric acid: AS100 at 119.84℃; for 10h; Reagent/catalyst; Temperature; Inert atmosphere; Autoclave; High pressure; | A 60% B 33.2% C 5.4% |
With tert-butyl alcohol over sulfonated hybrid silicas at 75℃; for 24h; Reagent/catalyst; |
tert-butyl methyl ether
glycerol
A
1,2-di-tert-butylglycerol ether
B
3-(tert-butoxy)propane-1,2-diol
C
1,3-di-tert-buthyl glycerol ether
D
tri-tert-butyl glycerol ether
Conditions | Yield |
---|---|
With A35 resin acid at 70℃; under 11251.1 Torr; for 24h; Inert atmosphere; | A n/a B n/a C 60% D n/a |
Conditions | Yield |
---|---|
With sulfuric acid at 25℃; for 12h; Molecular sieve; | 45% |
Conditions | Yield |
---|---|
at 100℃; for 1h; Catalytic behavior; Reagent/catalyst; Temperature; Concentration; Time; Autoclave; Inert atmosphere; | 11% |
With H-Beta zeolite at 74.84℃; for 24h; Catalytic behavior; Temperature; Time; Autoclave; | |
With sulfonated carbons from olive stones at 75℃; for 0.25h; Temperature; Microwave irradiation; High pressure; |
tert-butyl methyl ether
tri-tert-butyl glycerol ether
Conditions | Yield |
---|---|
With di-tert-butyl peroxide Irradiation; |
glycerol
isobutene
A
3-(tert-butoxy)propane-1,2-diol
B
1,3-di-tert-buthyl glycerol ether
C
tri-tert-butyl glycerol ether
Conditions | Yield |
---|---|
strong acidic catalyst at 80 - 100℃; |
Conditions | Yield |
---|---|
β-Zeolite at 85℃; under 4380.18 - 8000.32 Torr; for 3h; Product distribution / selectivity; | |
methanesulfonic acid at 70℃; for 6h; Product distribution / selectivity; | |
sulfuric acid at 66℃; for 10h; | |
With S-B(1.4) sulfonic acid-functionalized pentasyl-type zeolite for 24h; Reagent/catalyst; Concentration; Time; | |
With dodecylaminesulfonic acid-functionalised hexagonal mesoporous silica for 24h; Reagent/catalyst; Autoclave; |
glycerol
isobutene
A
2,2-dimethylhexane
B
tri-tert-butyl glycerol ether
C
tert-butyl alcohol
Conditions | Yield |
---|---|
sulfuric acid at 80℃; for 10h; Product distribution / selectivity; |