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92867-55-5

Basic Information
CAS No.: 92867-55-5
Name: Propane, 1,2,3-tris(1,1-dimethylethoxy)-
Article Data: 21
Molecular Structure:
Molecular Structure of 92867-55-5 (Propane, 1,2,3-tris(1,1-dimethylethoxy)-)
Formula: C15H32O3
Molecular Weight: 260.417
Synonyms: 1,2,3-tri-tert-butoxypropane;tri-tert-butyl-glycerol;1.2.3-Tri-tert-butoxypropan;tri-tert-butyl glycerol ether;glycerol tri-tert-butyl ether;
PSA: 27.69000
LogP: 3.80030
Synthetic route
56-81-5

glycerol

115-11-7

isobutene

A

162507-72-4

1,2-di-tert-butylglycerol ether

B

74338-98-0

3-(tert-butoxy)propane-1,2-diol

C

79808-30-3

1,3-di-tert-buthyl glycerol ether

D

92867-55-5

tri-tert-butyl glycerol ether

Conditions
ConditionsYield
With A35 resin acid at 75℃; under 11251.1 Torr; for 20h; Inert atmosphere;A n/a
B n/a
C 80%
D n/a
56-81-5

glycerol

75-65-0

tert-butyl alcohol

A

162507-72-4

1,2-di-tert-butylglycerol ether

B

74338-98-0

3-(tert-butoxy)propane-1,2-diol

C

79808-30-3

1,3-di-tert-buthyl glycerol ether

D

92867-55-5

tri-tert-butyl glycerol ether

Conditions
ConditionsYield
With 1-methyl-imidazolium p-toluenesulfonic acid at 100℃; under 11251.1 Torr; for 24h; Inert atmosphere;A n/a
B n/a
C 65%
D n/a
With unilamellar MFI zeolite nanosheet at 119.84℃; for 12h; Reagent/catalyst; Autoclave;
56-81-5

glycerol

75-65-0

tert-butyl alcohol

A

74338-98-0

3-(tert-butoxy)propane-1,2-diol

B

79808-30-3

1,3-di-tert-buthyl glycerol ether

C

92867-55-5

tri-tert-butyl glycerol ether

Conditions
ConditionsYield
With pillared clay treatedwith fuming sulfuric acid: AS100 at 119.84℃; for 10h; Reagent/catalyst; Temperature; Inert atmosphere; Autoclave; High pressure;A 60%
B 33.2%
C 5.4%
With tert-butyl alcohol over sulfonated hybrid silicas at 75℃; for 24h; Reagent/catalyst;
1634-04-4

tert-butyl methyl ether

56-81-5

glycerol

A

162507-72-4

1,2-di-tert-butylglycerol ether

B

74338-98-0

3-(tert-butoxy)propane-1,2-diol

C

79808-30-3

1,3-di-tert-buthyl glycerol ether

D

92867-55-5

tri-tert-butyl glycerol ether

Conditions
ConditionsYield
With A35 resin acid at 70℃; under 11251.1 Torr; for 24h; Inert atmosphere;A n/a
B n/a
C 60%
D n/a
1634-04-4

tert-butyl methyl ether

56-81-5

glycerol

92867-55-5

tri-tert-butyl glycerol ether

Conditions
ConditionsYield
With sulfuric acid at 25℃; for 12h; Molecular sieve;45%
56-81-5

glycerol

75-65-0

tert-butyl alcohol

92867-55-5

tri-tert-butyl glycerol ether

Conditions
ConditionsYield
at 100℃; for 1h; Catalytic behavior; Reagent/catalyst; Temperature; Concentration; Time; Autoclave; Inert atmosphere;11%
With H-Beta zeolite at 74.84℃; for 24h; Catalytic behavior; Temperature; Time; Autoclave;
With sulfonated carbons from olive stones at 75℃; for 0.25h; Temperature; Microwave irradiation; High pressure;
1634-04-4

tert-butyl methyl ether

92867-55-5

tri-tert-butyl glycerol ether

Conditions
ConditionsYield
With di-tert-butyl peroxide Irradiation;
56-81-5

glycerol

115-11-7

isobutene

A

74338-98-0

3-(tert-butoxy)propane-1,2-diol

B

79808-30-3

1,3-di-tert-buthyl glycerol ether

C

92867-55-5

tri-tert-butyl glycerol ether

Conditions
ConditionsYield
strong acidic catalyst at 80 - 100℃;
56-81-5

glycerol

115-11-7

isobutene

92867-55-5

tri-tert-butyl glycerol ether

Conditions
ConditionsYield
β-Zeolite at 85℃; under 4380.18 - 8000.32 Torr; for 3h; Product distribution / selectivity;
methanesulfonic acid at 70℃; for 6h; Product distribution / selectivity;
sulfuric acid at 66℃; for 10h;
With S-B(1.4) sulfonic acid-functionalized pentasyl-type zeolite for 24h; Reagent/catalyst; Concentration; Time;
With dodecylaminesulfonic acid-functionalised hexagonal mesoporous silica for 24h; Reagent/catalyst; Autoclave;
56-81-5

glycerol

115-11-7

isobutene

A

590-73-8

2,2-dimethylhexane

B

92867-55-5

tri-tert-butyl glycerol ether

C

75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
sulfuric acid at 80℃; for 10h; Product distribution / selectivity;
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