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CAS No.: | 73895-98-4 |
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Name: | 2-Bromoo-4-methyl-6-aminopyridine |
Article Data: | 6 |
Molecular Structure: | |
Formula: | C6H7 Br N2 |
Molecular Weight: | 187.039 |
Synonyms: | 4-Picoline,2-amino-6-bromo- (7CI); 6-Amino-2-bromo-4-methylpyridine;6-Bromo-4-methylpyridin-2-ylamine |
Density: | 1.593g/cm3 |
Melting Point: | 115 °C |
Boiling Point: | 293.675°C at 760 mmHg |
Flash Point: | 131.41°C |
PSA: | 38.91000 |
LogP: | 2.31590 |
1,3-dicyano-2-methyl-2-hydroxypropane
6-bromo-4-methylpyridine-2-amine
Conditions | Yield |
---|---|
With sodium hydroxide; hydrogen bromide In acetic acid; ethyl acetate | 66% |
With hydrogen bromide; acetic acid at 20℃; for 2h; |
2-chloromethyl-2-methyloxiran
1,3-dicyano-2-methyl-2-hydroxypropane
6-bromo-4-methylpyridine-2-amine
Conditions | Yield |
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With sodium hydroxide; hydrogen bromide In hydrogenchloride; water; acetic acid; ethyl acetate |
acetic anhydride
6-bromo-4-methylpyridine-2-amine
N-(6-bromo-4-methyl-pyridin-2-yl)-acetamide
Conditions | Yield |
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With pyridine; dmap | 89% |
6-bromo-4-methylpyridine-2-amine
p-methoxybenzyl chloride
Conditions | Yield |
---|---|
Stage #1: 6-bromo-4-methylpyridine-2-amine With sodium hydride In N,N-dimethyl-formamide at 0 - 25℃; for 1h; Stage #2: p-methoxybenzyl chloride In N,N-dimethyl-formamide at 25℃; for 2h; | 87.5% |
2-(4,4-difluorocyclohex-1-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
6-bromo-4-methylpyridine-2-amine
Conditions | Yield |
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With potassium phosphate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 In 1,4-dioxane; water at 100℃; for 16h; | 83% |
6-bromo-4-methylpyridine-2-amine
2,5-hexanedione
2-bromo-6-(2,5-dimethyl-1H-pyrrol-1-yl)-4-methylpyridine
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In toluene at 150℃; for 1h; Microwave irradiation; | 82% |
With toluene-4-sulfonic acid In toluene for 1.5h; Paal-Knorr reaction; Heating; | |
With sodium acetate; acetic acid In toluene for 48h; Heating / reflux; |
6-bromo-4-methylpyridine-2-amine
Bromoacetaldehyde diethyl acetal
Conditions | Yield |
---|---|
With sodium hydrogencarbonate In water; ethyl acetate | 76% |
para-xylene
6-bromo-4-methylpyridine-2-amine
1-bromo-3,6,9-trimethylpyrido[1,2-a]benzimidazole
Conditions | Yield |
---|---|
With [bis(acetoxy)iodo]benzene at 40℃; for 12h; regioselective reaction; | 76% |
di-tert-butyl dicarbonate
6-bromo-4-methylpyridine-2-amine
tert-butyl (6-bromo-4-methylpyridin-2-yl)carbamate
Conditions | Yield |
---|---|
With triethylamine In tert-butyl alcohol at 20℃; for 24h; | 76% |
2-chloroethanal
6-bromo-4-methylpyridine-2-amine
Conditions | Yield |
---|---|
In ethanol for 20h; Reflux; | 75% |