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Silanamine,N-(4-bromophenyl)-1,1,1-trimethyl-N-(trimethylsilyl)-

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Name

Silanamine,N-(4-bromophenyl)-1,1,1-trimethyl-N-(trimethylsilyl)-

EINECS N/A
CAS No. 5089-33-8 Density 1.125 g/cm3
PSA 3.24000 LogP 4.92530
Solubility N/A Melting Point N/A
Formula C12H22BrNSi2 Boiling Point 298.5 °C at 760 mmHg
Molecular Weight 316.388 Flash Point 134.3 °C
Transport Information N/A Appearance N/A
Safety 26-36 Risk Codes 36/37/38
Molecular Structure Molecular Structure of 5089-33-8 (4-BROMO-N,N-BIS(TRIMETHYLSILYL)ANILINE) Hazard Symbols IrritantXi
Synonyms

Disilazane,2-(p-bromophenyl)-1,1,1,3,3,3-hexamethyl- (7CI,8CI);4-Bromo-N,N-bis(trimethylsilyl)aniline;N,N-Bis(trimethylsilyl)-4-bromoaniline;N,N-Bis(trimethylsilyl)-4-bromobenzenamine;N,N-Bis(trimethylsilyl)-p-bromoaniline;N-(4-Bromophenyl)-1,1,1-trimethyl-N-(trimethylsilyl)silanamine;p-Bromo-N,N-bis(trimethylsilyl)aniline;Benzenamine, 4-bromo-N,N-bis(trimethylsilyl)-;N-(4-Bromophenyl)-1,1,1-trimethyl-N-(trimethylsilyl)silanamine;

Article Data 14

Silanamine,N-(4-bromophenyl)-1,1,1-trimethyl-N-(trimethylsilyl)- Specification

The Silanamine,N-(4-bromophenyl)-1,1,1-trimethyl-N-(trimethylsilyl)-, with the CAS registry number 5089-33-8, has the systematic name of N-(4-bromophenyl)-1,1,1-trimethyl-N-(trimethylsilyl)silanamine. It belongs to the product following product categories: Nitrogen Compounds; Organic Building Blocks; Protected Amines. And the molecular formula of the chemical is C12H22BrNSi2.

The characteristics of Silanamine,N-(4-bromophenyl)-1,1,1-trimethyl-N-(trimethylsilyl)- are as followings: (1)ACD/LogP: 5.05; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): 4.73; (4)ACD/LogD (pH 7.4): 5.04; (5)ACD/BCF (pH 5.5): 1935.32; (6)ACD/BCF (pH 7.4): 3992.47; (7)ACD/KOC (pH 5.5): 6356; (8)ACD/KOC (pH 7.4): 13112.11; (9)#H bond acceptors: 1; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 3; (12)Polar Surface Area: 3.24 Å2; (13)Index of Refraction: 1.511; (14)Molar Refractivity: 84.22 cm3; (15)Molar Volume: 281.1 cm3; (16)Polarizability: 33.38×10-24cm3; (17)Surface Tension: 26.4 dyne/cm; (18)Density: 1.125 g/cm3; (19)Flash Point: 134.3 °C; (20)Enthalpy of Vaporization: 53.84 kJ/mol; (21)Boiling Point: 298.5 °C at 760 mmHg; (22)Vapour Pressure: 0.00127 mmHg at 25°C.

Preparation of Silanamine,N-(4-bromophenyl)-1,1,1-trimethyl-N-(trimethylsilyl)-: This chemical can be prepared by 4-bromo-aniline andchloro-trimethyl-silane. The reaction will need reagent BuLi, and the menstruum tetrahydrofuran and hexane. And the yield is about 68%. 

Uses of Silanamine,N-(4-bromophenyl)-1,1,1-trimethyl-N-(trimethylsilyl)-: It can react with N-(2-chloro-ethyl)-benzamide to produce N-(4-amino-phenethyl)-benzamide. This reaction will need reagent buthyllithium and lithium naphthalenide, and the menstruum tetrahydrofuran and hexane. And the yield is about 53%. 

You should be cautious while dealing with this chemical. It irritates to eyes, respiratory system and skin. Therefore, you had better take the following instructions: Wear suitable protective clothing, and if in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice.

Addtionally, the following datas could be converted into the molecular structure:
(1)SMILES: Brc1ccc(N([Si](C)(C)C)[Si](C)(C)C)cc1
(2)InChI: InChI=1/C12H22BrNSi2/c1-15(2,3)14(16(4,5)6)12-9-7-11(13)8-10-12/h7-10H,1-6H3
(3)InChIKey: YJYMZGDBOMZWSR-UHFFFAOYAV

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