DICHLOROBIS[2-(DI-I-PROPYLPHOSPHINO)ETHYLAMINE]RUTHENIUM (II), MIN

Base Information

• Chemical Name: DICHLOROBIS[2-(DI-I-PROPYLPHOSPHINO)ETHYLAMINE]RUTHENIUM (II), MIN
• CAS No.: 1092372-90-1
• Molecular Formula: C16H40Cl2N2P2Ru
• Molecular Weight: 494.43
• Hs Code.: 28439090
• Mol file: 1092372-90-1.mol

Synonyms:DICHLOROBIS[2-(DI-I-PROPYLPHOSPHINO)ETHYLAMINE]RUTHENIUM (II), MIN;Dichlorobis(2-(diisopropylphosphino)-ethylamine)ruthenium(II) 97%;Dichlorobis[2-(di-i-propylphosphino)ethylaMine]rutheniuM(II),97%

Chemical Property of DICHLOROBIS[2-(DI-I-PROPYLPHOSPHINO)ETHYLAMINE]RUTHENIUM (II), MIN

Chemical Property:

• Melting Point: 154-157°C
• PSA: 79.22000
• LogP: -0.10380

Purity/Quality:

97% ^*data from raw suppliers

Dichlorobis[2-(di-i-propylphosphino)ethylamine]ruthenium(II), min. 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of DICHLOROBIS[2-(DI-I-PROPYLPHOSPHINO)ETHYLAMINE]RUTHENIUM (II), MIN

There total 5 articles about DICHLOROBIS[2-(DI-I-PROPYLPHOSPHINO)ETHYLAMINE]RUTHENIUM (II), MIN which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

2-(di-isopropylphosphanyl)-1-aminoethane (1053657-14-9) → trans-RuCl2((i-Pr)2P(CH2)2NH2)2 (1092372-90-1)

Guidance literature:

In diethyl ether; toluene; at 20 ℃; for 20h; Heating / reflux;

Reference yield: 81.0%

cyclooctadiene ruthenium(II) dichloride (50982-12-2) + 2-(di-isopropylphosphanyl)-1-aminoethane (1053657-14-9) → trans-RuCl2((i-Pr)2P(CH2)2NH2)2 (1092372-90-1)

Guidance literature:

In toluene; a mixt. of complex and aminophosphine was refluxed in toluene under Ar for 6 h, the mixt. was cooled to room temp.; ether was added, suspn. was stirred for 1 h, filtered, washed with etherand dried under vac.; elem. anal.;

DOI:10.1039/b911459a

Reference yield: 55.0%

bis-μ-dichloro(1,5-cyclooctadiene)ruthenium(II) + [iPr2P(H)CH2CH2NH3][BF4]2 → RuCl2(i-Pr2PCH2CH2NH2)2 (1092372-90-1)

Guidance literature:

With triethylamine; In toluene; for 16h; Inert atmosphere; Reflux;

upstream raw materials:

2-(di-isopropylphosphanyl)-1-aminoethane

cyclooctadiene ruthenium(II) dichloride

Refernces

• 1、 -. "METHOD FOR PREPARING A METAL CATALYST". Page/Page column 13. . Retrieved 2012/03/10.
• 2、 Jia, Wenli,Chen, Xuanhua,Guo, Rongwei,Sui-Seng, Christine,Amoroso, Dino,Lough, Alan J.,Abdur-Rashid, Kamaluddin. "Aminophosphine ligands R2P(CH2)nNH 2 and ruthenium hydrogenation catalysts RuCl2(R 2P(CH2)nNH2)2". . p. 8301 - 8307. Retrieved 2010/03/04.