1053657-14-9

Basic information

• Product Name: 2-(Di-i-propylphosphino)ethylamine, min. 97% (10 wt% in THF)
• Synonyms: 2-(Di-i-propylphosphino)ethylamine, min. 97% (10 wt% in THF);2-(Di-i-propylphosphino)ethylaMine;97% (10 wt% in THF);2-(Diisopropylphosphino)ethylaMine, 10 wt.% solution in THF;2-(Diisopropylphosphino)ethylaMine, 10% w/w soln. in THF;2-[Bis(1-methylethyl)phosphino]ethanamine;2-(Diisopropylphosphino)ethanamine;(2-Aminoethyl)diisopropylphosphine
• CAS NO: 1053657-14-9
• Molecular Formula: C₈H₂₀NP
• Molecular Weight: 161.224861
• Product Categories: Achiral Phosphine;Alkyl Phosphine
• Mol File: 1053657-14-9.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 208.8±23.0 °C(Predicted)
• Flash Point: -16℃
• Appearance: pale yellow to colorless/liquid
• Density: 0.872 g/mL at 25 °C
• Refractive Index: n20/D1.416
• PKA: 10.33±0.10(Predicted)
• Sensitive: Air Sensitive
• CAS DataBase Reference: 2-(Di-i-propylphosphino)ethylamine, min. 97% (10 wt% in THF)(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(Di-i-propylphosphino)ethylamine, min. 97% (10 wt% in THF)(1053657-14-9)
• EPA Substance Registry System: 2-(Di-i-propylphosphino)ethylamine, min. 97% (10 wt% in THF)(1053657-14-9)

Safety Data

• Hazard Codes: F,C
• Statements: 10-17-34-40-37-19-11
• Safety Statements: 26-36/37/39-45-16
• RIDADR: UN 2924 8(3) / PGII
• WGK Germany: 3
• HazardClass: 3
• Hazardous Substances Data: 1053657-14-9(Hazardous Substances Data)

Usage

Uses

Reactant for synthesis of ruthenium hydrogenation catalysts

Upstream product

• 40244-90-4 Chlorodiisopropylphosphane 
• 61883-48-5 N, N′-bis(trimethylsilyl)-2-chloroethanamine 
• 20491-53-6 di-isopropylphosphine 

Downstream Products

• 1092372-90-1 trans-RuCl2((i-Pr)2P(CH2)2NH2)2 
• 1092372-90-1 RuCl₂(iPr₂PCH₂CH₂NH₂)₂ 

Relevant articles and documents

Novel method for preparing butanol by catalyzing ethanol condensation by virtue of manganese

The invention discloses a novel method for preparing butanol by catalyzing ethanol condensation by virtue of manganese. A manganese catalyst adopted in the method is a manganese complex shown in a formula I, a formula II, a formula III or a formula IV. Based on the manganese complex, the invention provides a method for preparing butanol through ethanol coupling based on catalysis of cheap manganese metal, high catalytic activity (TON=114120, wherein TOF of early 12h is 3078/h) and 92% butanol selectivity (figure 1) are shown. The method disclosed by the invention has the advantages that biomass resources are efficiently utilized, and especially an important technical support and theoretical guidance are provided for production of high-quality biofuel, catalytic activation and transformation of a biomass platform compound and design of a corresponding cheap and efficient catalyst.

METHOD FOR THE PREPARATION OF AMINOPHOSPHINE LIGANDS AND THEIR USE IN METAL CATALYSTS

The present application is directed to i) a two-step method for synthesizing phosphme-ammophosphme (P,N,P) ligands, ii) the use of such ligands in the preparation of metal complexes as hydrogenation catalysts, and iii) ammophosphme (P,N) and phosphme-ammo