1,10-PHENANTHROLINE IRON(II) PERCHLORATE

Base Information

• Chemical Name: 1,10-PHENANTHROLINE IRON(II) PERCHLORATE
• CAS No.: 14586-54-0
• Molecular Formula: C36H24Cl2FeN6O8
• Molecular Weight: 795.36
• Mol file: 14586-54-0.mol

Synonyms:1,10-PHENANTHROLINE IRON(II) PERCHLORATE;O-PHENANTHROLINE FERROUS PERCH LORATE;TRIS-(1,10-PHENANTHROLINE) FERROUS PERCHLORATE;tris(1,10-phenanthroline-n1,n19)-iron(2++(oc-6-11)-iron(2++diperchlorate;tris(1,10-phenanthroline-N1,N10)iron diperchlorate;1,10-Phenanthroline Iron(Ⅱ) Perchlorate;1,10-Phenanthroline ferrous perchlorate

Chemical Property of 1,10-PHENANTHROLINE IRON(II) PERCHLORATE

Chemical Property:

• Boiling Point: 365.1°Cat760mmHg
• Flash Point: 164.8°C
• PSA: 225.88000
• Density: g/cm³
• LogP: 8.77510
• Water Solubility.: Slightly soluble in water.

Purity/Quality:

99% ^*data from raw suppliers

1,10-PHENFERROUSPERCHL ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 1,10-Phenanthroline iron(II) perchlorate is used as an oxidation, reduction indicator. It is used for the detection, identification, analysis, of chemical, biological, or pathologic processes or conditions. Agents that are capable of inserting themselves between the successive bases in DNA, thus kinking, uncoiling or otherwise deforming it and therefore preventing its proper functioning. They are used in the study of DNA.

Technology Process of 1,10-PHENANTHROLINE IRON(II) PERCHLORATE

There total 2 articles about 1,10-PHENANTHROLINE IRON(II) PERCHLORATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

tris(1,10-phenantholine)iron(III) perchlorate + (t-butyl)trimethylstannane (3531-47-3) + acetonitrile (75-05-8,26809-02-9) → tris(1,10-phenanthroline)iron(II) perchlorate (14586-54-0) + N-tert-butylacetamide (762-84-5) + trimethyltin(IV)chloride (1066-45-1) + isobutene (115-11-7,15220-85-6)

Guidance literature:

With ammonia; In acetonitrile; t-BuSnMe3 in CH3CN added to Fe(phen)3(ClO4)3 in CH3CN at 22°C under Ar and soln. stirred for 2 h, drop water added, Fe(II) complex filtered, filtrate dried with MgSO4 and treated with anhyd. aq. NH3, Sn product treated with HCl and sublimed;

DOI:10.1021/ja00369a030

Reference yield:

(+)589-tris(1,10-phenanthroline)iron(II) perchlorate dihydrate → 1,10-Phenanthroline (66-71-7) + tris(1,10-phenanthroline)iron(II) perchlorate (14586-54-0)

Guidance literature:

In water; at 32°C, Fe complex dissolved in water, stirred with or without some nucleophiles; not isolated, detected by UV; Kinetics;

DOI:10.1246/bcsj.55.1014

Reference yield:

tris(1,10-phenanthroline)iron(II) perchlorate (14586-54-0) + neptunyl(VI) perchlorate → tris(1,10-phenanthroline)iron(III) (13479-49-7) + neptunium(V) (86954-34-9)

Guidance literature:

In perchloric acid; Np(ClO4)6 was reacted with Fe-complex at 1.0, 12.0, 25.0 and 35.0°C in aq. HClO4; Kinetics;

DOI:10.1021/ic50225a074

upstream raw materials:

(t-butyl)trimethylstannane

acetonitrile

Downstream raw materials:

tris(1,10-phenanthroline)iron(III)

neptunium(V)

Refernces

• 1、 Rollick,Kochi. "OXIDATION-REDUCTION MECHANISMS - INNER-SPHERE AND OUTER-SPHERE ELECTRON TRANSFER IN THE REDUCTION OF IRON(III), RUTHENIUM(III), AND OSMIUM(III) COMPLEXES BY ALKYL RADICALS. MECHANISMS -". . p. 1319 - 1330. Retrieved 2007/10/02.