tert-butyl(trimethyl)stannane

Base Information

• Chemical Name: tert-butyl(trimethyl)stannane
• CAS No.: 3531-47-3
• Molecular Formula: C7H18Sn
• Molecular Weight: 220.93
• Mol file: 3531-47-3.mol

Synonyms:

Chemical Property of tert-butyl(trimethyl)stannane

Chemical Property:

• Vapor Pressure: 4.866mmHg at 25°C

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tert-butyl(trimethyl)stannane

There total 8 articles about tert-butyl(trimethyl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

tertiary butyl chloride (507-20-0) + trimethylstannyl sodium (16643-09-7) → hexamethyldistannane (661-69-8) + (t-butyl)trimethylstannane (3531-47-3)

Guidance literature:

In further solvent(s); under argon, equimolar amounts, at 0°C in tetraglyme; GLC;

Reference yield: 82.0%

t-butyl bromide (507-19-7) + trimethylstannyl sodium (16643-09-7) → hexamethyldistannane (661-69-8) + (t-butyl)trimethylstannane (3531-47-3)

Guidance literature:

In further solvent(s); under argon, equimolar amounts, at 0°C in tetraglyme; GLC;

Reference yield: 82.0%

trimethylstannyl sodium (16643-09-7) + tert-Butyl iodide (558-17-8) → hexamethyldistannane (661-69-8) + (t-butyl)trimethylstannane (3531-47-3)

Guidance literature:

In tetrahydrofuran; under argon, equimolar amounts, at 0°C; GLC;

upstream raw materials:

t-butyl bromide

trimethylstannyl sodium

tertiary butyl chloride

tert-Butyl iodide

Downstream raw materials:

N-tert-butylacetamide

isobutene

5-tert-Butyl-1,2,4-Benzenetricarbonitrile

2-(tert-butyl)succinic acid dimethyl ester

Refernces

• 1、 Farah, Dan,Karol, Thomas J.,Kuivila, Henry G.. "Nucleophilicity vs. basicity in reactions of n-butyllithium and tert-butyllithium with tetramethylstannane". . p. 662 - 666. Retrieved 2008/10/08.