Nickel dibutyldithiocarbamate

Base Information

• Chemical Name: Nickel dibutyldithiocarbamate
• CAS No.: 13927-77-0
• Molecular Formula: 2(C9H18NS2)^.Ni
• Molecular Weight: 467.451
• Hs Code.: 2930.20
• European Community (EC) Number: 237-696-2
• Mol file: 13927-77-0.mol

Synonyms:Nickel dibutyldithiocarbamate;13927-77-0;N,N-dibutylcarbamodithioate;nickel(2+);nickel(2+) bis(dibutyldithiocarbamate);Nickel dibutyl dithiocarbamate;Nickel, bis(dibutylcarbamodithioato-.kappa.S,.kappa.S')-, (SP-4-1)-;Nickel di-n-butyldithiocarbamate;MFCD00067273;AKOS015913841;Dibutyldithiocarbamic Acid Nickel Salt;nickel dibutyldithiocarbamate, AldrichCPR;CS-0085577;NS00084964;E76028;Nickel, bis(dibutylcarbamodithioato-.kappa.S,.kappa

Chemical Property of Nickel dibutyldithiocarbamate

Chemical Property:

• Appearance/Colour: COA
• Vapor Pressure: 0.0144mmHg at 25°C
• Melting Point: 86 °C
• Boiling Point: 257.7 °C at 760 mmHg
• Flash Point: 109.6 °C
• PSA: 121.26000
• Density: 1.26 g/cm³
• LogP: 6.73950
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Solubility.: Practically insoluble in water
• Water Solubility.: 8.93μg/L at 20℃
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 12
• Exact Mass: 466.111476
• Heavy Atom Count: 25
• Complexity: 272

Purity/Quality:

99% ^*data from raw suppliers

Nickel(II) Dibutyldithiocarbamate >97.0%(T) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Plastics & Rubber -> Dithiocarbamates (Rubber)
• Canonical SMILES: CCCCN(CCCC)C(=S)[S-].CCCCN(CCCC)C(=S)[S-].[Ni+2]
• Uses: Antioxidant for synthetic rubbers.

Technology Process of Nickel dibutyldithiocarbamate

There total 4 articles about Nickel dibutyldithiocarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

nickel(II) chloride hexahydrate + sodium N,N-dibutyldithiocarbamate monohydrate → bis(N,N-dibutyldithiocarbamato-S,S')nickel(II) (13927-77-0)

Guidance literature:

In water; ligand in H2O added to Ni salt in H2O under stirring; decanted, filtered, dried (air), recrystd.(EtOH/CHCl3 1:1), elem. anal.;

DOI:10.1007/s11173-005-0157-4

Reference yield:

carbon disulfide (75-15-0,12122-00-8) + nickel(II) chloride hexahydrate + dibutylamine (111-92-2) → bis(N,N-dibutyldithiocarbamato-S,S')nickel(II) (13927-77-0)

Guidance literature:

With KOH; Na-acetate; In water; reaction of (C4H9)2NH with 1 mol CS2 (dissolved in equiv. amt. of 20% aq. KOH), addn. of 1 mol aq. NiCl2 and 3 mol Na-acetate; extn. with acetone, recrystn. from acetone;

Reference yield:

nickel (7440-02-0) + sodium dibutyl dithiocarbamate (136-30-1) → bis(N,N-dibutyldithiocarbamato-S,S')nickel(II) (13927-77-0)

Guidance literature:

In ethanol; addn. of Ni powder to the dithiocarbamate in ethanol; stirring for 5 h;; Kinetics;

DOI:10.1016/S0277-5387(00)84424-1

upstream raw materials:

carbon disulfide

dibutylamine

nickel

sodium dibutyl dithiocarbamate

Downstream raw materials:

gersdorffite

Refernces