1,1-Dimethylpiperidinium iodide

Base Information

• Chemical Name: 1,1-Dimethylpiperidinium iodide
• CAS No.: 3333-08-2
• Molecular Formula: C7H16 N . I
• Molecular Weight: 241.115
• Hs Code.: 2933399090
• European Community (EC) Number: 636-479-3
• NSC Number: 7409
• UNII: 4E7ZBZ4V52
• DSSTox Substance ID: DTXSID10954964
• Wikidata: Q27259475
• Mol file: 3333-08-2.mol

Synonyms:1,1-Dimethylpiperidinium iodide;Dimethylpiperidinium iodide;N,N-Dimethylpiperidinium iodide;3333-08-2;1,1-dimethylpiperidin-1-ium iodide;1,1-dimethylpiperidin-1-ium;iodide;1,1-DIMETHYLPIPERIDINIUMIODIDE;4E7ZBZ4V52;NSC 7409;NSC-7409;PIPERIDINIUM, 1,1-DIMETHYL-, IODIDE;MEPIQUAT IODIDE;Dimethylpiperidiniumjodid;starbld0016513;UNII-4E7ZBZ4V52;SCHEMBL363758;DTXSID10954964;NSC7409;Piperidinium,1-dimethyl-, iodide;AKOS024332221;LS-116519;Mepiquat iodide-(methyl-d3), analytical standard;PIPERIDINIUM, 1,1-DIMETHYL-, IODIDE (1:1);Q27259475

Chemical Property of 1,1-Dimethylpiperidinium iodide

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: -1.79050
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 241.03275
• Heavy Atom Count: 9
• Complexity: 68.5

Purity/Quality:

99%min ^*data from raw suppliers

1,1-DIMETHYLPIPERIDINIUM IODIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[N+]1(CCCCC1)C.[I-]

Technology Process of 1,1-Dimethylpiperidinium iodide

There total 9 articles about 1,1-Dimethylpiperidinium iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

N-methylcyclohexylamine (626-67-5) + methyl iodide (74-88-4) → N,N-dimethylpiperidinium iodide (3333-08-2)

Guidance literature:

In diethyl ether; Ambient temperature;

DOI:10.1016/S0040-4020(01)85267-4

Reference yield: 84.0%

N-methylcyclohexylamine (626-67-5) + benzoyl iodide (618-38-2) → N-benzoylpiperidine (776-75-0) + N-(5-iodopentyl)-N-methylbenzamide (1356267-34-9) + N,N-dimethylpiperidinium iodide (3333-08-2)

Guidance literature:

In dichloromethane; at 20 ℃; for 6h;

DOI:10.1134/S1070428010060047

Reference yield:

N-methylcyclohexylamine (626-67-5) + methyl (2Z)-3-iodoprop-2-enoate (6214-23-9) → (E)-methyl 3-(piperidin-1-yl)acrylate (5762-45-8,7542-91-8,90608-65-4) + N,N-dimethylpiperidinium iodide (3333-08-2)

Guidance literature:

upstream raw materials:

piperidine

methyl iodide

N-methylcyclohexylamine

di(N-piperidinyl)methane

Downstream raw materials:

N-methylcyclohexylamine

1-piperidin-1-yl-ethanone

mepiquat chloride

Refernces

• 1、 Chen, Nanjun,Fan, Jiantao,Hu, Chuan,Jin, Yiqi,Lee, Young Moo,Li, Hui,Liu, Haijun,Wu, Bo,Xu, Shaoyi. "Insight into the Alkaline Stability of N-Heterocyclic Ammonium Groups for Anion-Exchange Polyelectrolytes". supporting information. p. 19272 - 19280. Retrieved 2021/07/25.
• 2、 Voronkov,Tsyrendorzhieva,Rakhlin. "Acyl iodides in organic synthesis. Reactions with morpholine, piperidine, and N-hydrocarbylpiperidines". experimental part. p. 794 - 797. Retrieved 2010/10/04.