4-Nitro-p-terphenyl

Base Information

• Chemical Name: 4-Nitro-p-terphenyl
• CAS No.: 10355-53-0
• Molecular Formula: C18H13NO2
• Molecular Weight: 275.307
• Hs Code.: 29042000
• European Community (EC) Number: 233-775-0
• NSC Number: 506434
• UNII: O992334O9F
• DSSTox Substance ID: DTXSID30145897
• Nikkaji Number: J236.475A
• Wikidata: Q72496268
• Mol file: 10355-53-0.mol

Synonyms:4-Nitro-p-terphenyl;10355-53-0;4-nitro-1,1':4',1''-terphenyl;1-(4-nitrophenyl)-4-phenylbenzene;p-Terphenyl, 4-nitro-;1,1':4',1''-TERPHENYL, 4-NITRO-;EINECS 233-775-0;NSC 506434;BRN 2217021;4-Nitro-1,1':4':1"-terphenyl;NSC-506434;O992334O9F;3-05-00-02299 (Beilstein Handbook Reference);NSC506434;4-Nitro-(para-terphenyl);1,1''-Terphenyl, 4-nitro-;N-METHYLQUIPAZINEDIMALEATE;UNII-O992334O9F;DTXSID30145897;AMY38640;4-(4-nitrophenyl)-1,1'-biphenyl;MFCD00044846;4-Nitro-1,1':4':1''-terphenyl;AKOS015833471;AS-59851;4''-Nitro-[1,1';4',1'']terphenyl;LS-148793;FT-0636689;N0610;C14052

Chemical Property of 4-Nitro-p-terphenyl

Chemical Property:

• Appearance/Colour: Light yellow crystalline powder
• Vapor Pressure: 1.71E-08mmHg at 25°C
• Melting Point: 214 °C
• Refractive Index: 1.625
• Boiling Point: 468.3 °C at 760 mmHg
• Flash Point: 224.4 °C
• PSA: 45.82000
• Density: 1.187 g/cm³
• LogP: 5.45200
• Storage Temp.: Sealed in dry,Room Temperature
• XLogP3: 5.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 275.094628657
• Heavy Atom Count: 21
• Complexity: 330

Purity/Quality:

98%,99%, ^*data from raw suppliers

4-Nitro-P-terphenyl ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=CC=C(C=C2)C3=CC=C(C=C3)[N+](=O)[O-]

Technology Process of 4-Nitro-p-terphenyl

There total 18 articles about 4-Nitro-p-terphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

4-biphenylboronic acid (5122-94-1) + para-nitrophenyl bromide (586-78-7) → 4-nitro-p-terphenyl (10355-53-0)

Guidance literature:

With potassium carbonate; In water; at 100 ℃; for 0.5h; Microwave irradiation;

DOI:10.1039/c4gc00748d

Reference yield: 85.0%

[1,1';4',1'']terphenyl (92-94-4,94363-13-0) → 4-nitro-p-terphenyl (10355-53-0)

Guidance literature:

With nitric acid; In acetic acid;

DOI:10.1021/ac00280a019

Reference yield: 68.0%

para-nitrophenyl bromide (586-78-7) + potassium phenyltrifluoborate + potassium 4-bromophenyltrifluoroborate (374564-35-9) → 4-nitro-p-terphenyl (10355-53-0)

Guidance literature:

With choline chloride; palladium diacetate; sodium carbonate; glycerol; at 60 ℃; for 5h;

DOI:10.1002/cssc.201801382

upstream raw materials:

p-nitrobenzenediazonium

biphenyl

4-Cyclohexyl-4'-nitro-biphenyl

N-biphenyl-4-yl-N-nitroso-acetamide

Downstream raw materials:

<4-(allyloxy)benzoyloxy>-p-terfenyl

3-Nitro-4-propionylamino-p-terphenyl

Refernces

• 1、 Jansa, Josef,?ezní?ek, Tomá?,Dostál, Libor,R??i?ková, Zdena,Bure?, Filip,Jambor, Roman. "Amidophosphine-stabilized palladium complexes catalyse Suzuki–Miyaura cross-couplings in aqueous media". . p. 1036 - 1042. Retrieved 2016.
• 2、 Splies,R.G.. "-". . p. 2601 - 2602. Retrieved 1961.
• 3、 Grieve,Hey. "-". . p. 108,112. Retrieved 1938.
• 4、 Dilauro, Giuseppe,García, Sergio Mata,Tagarelli, Donato,Vitale, Paola,Perna, Filippo M.,Capriati, Vito. "Ligand-Free Bioinspired Suzuki–Miyaura Coupling Reactions using Aryltrifluoroborates as Effective Partners in Deep Eutectic Solvents". . p. 3495 - 3501. Retrieved 2018/09/21.