Diethyl dithiophosphate ammonium salt

Base Information

• Chemical Name: Diethyl dithiophosphate ammonium salt
• CAS No.: 1068-22-0
• Molecular Formula: C4H11 O2 P S2 . H3 N
• Molecular Weight: 203.266
• Hs Code.: 2931900090
• European Community (EC) Number: 213-942-4
• NSC Number: 8159
• Wikidata: Q2645893
• Wikipedia: Ammonium_diethyl_dithiophosphate
• Mol file: 1068-22-0.mol

Synonyms:1068-22-0;Ammonium o,o-diethyldithiophosphate;Diethyl dithiophosphate ammonium salt;O,O-Diethyl Dithiophosphate Ammonium Salt;azane;diethoxy-sulfanyl-sulfanylidene-lambda5-phosphane;Ammonium O,O'-diethyldithiophosphate;S-Ammonium O,O'-diethyl phosphorodithioate;NSC-8159;Diethyl dithiophosphate, ammonium salt;WLN: SHPS&O2&O2 &ZH;NSC8159;Ammonium,O-diethyl phosphorodithioate;AKOS015916229;AS-62448;O,O-diethyl sulfanylphosphonothioate amine;Diethyl dithiophosphate ammonium salt, 95%;FT-0633275;Ammonium O,O-Diethyldithiophosphate, Typically;J-001658;Q2645893;Phosphorodithioic acid,O-diethyl ester, ammonium salt;O,O-diethyl S-hydrogen phosphorodithioate, ammonia salt

Chemical Property of Diethyl dithiophosphate ammonium salt

Chemical Property:

• Appearance/Colour: white powder
• Vapor Pressure: 0.0153mmHg at 25°C
• Melting Point: 163-169oC
• Boiling Point: 232.7°Cat760mmHg
• Flash Point: 94.5°C
• PSA: 102.40000
• Density: 1.214g/cm³
• LogP: 3.18820
• Storage Temp.: ?20°C
• Water Solubility.: Soluble in water, methanol, ethanol, pyridine, acetone & ammonia. Insoluble in ethyl acetate, methyl chloride and chloroform
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 4
• Exact Mass: 203.02035803
• Heavy Atom Count: 10
• Complexity: 107

Purity/Quality:

98%,99%, ^*data from raw suppliers

O,O-Diethyl dithiophosphate ammonium salt ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn,T,F
• Hazard Codes: Xn,T,F
• Statements: 20/21/22-39/23/24/25-23/24/25-11
• Safety Statements: 36-45-36/37-16-7

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCOP(=S)(OCC)S.N
• Uses: O,O-Diethyl Dithiophosphate AMMoniuM Salt can be used in the synthesis of novel phosphorothioates and phosphorodithioates Diethyl dithiophosphate ammonium salt can be used in the extraction of arsenic. It is used as a source of the (C2H5O)2PS2- ligand in coordination chemistry and in analytical chemistry for determination of various ions. It can be obtained by the reaction of phosphorus pentasulfide with ethanol and ammonia.

Technology Process of Diethyl dithiophosphate ammonium salt

There total 5 articles about Diethyl dithiophosphate ammonium salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

ethanol (64-17-5) → diethyl dithiophosphate ammonium salt (1068-22-0)

Guidance literature:

With aluminum oxide; tetraphosphorus decasulfide; ammonium acetate; for 0.0166667h; microwave irradiation;

DOI:10.1055/s-2004-829176

Reference yield: 87.0%

{Mo2(N(C6H4CH3))2(S2P(OC2H5)2)2S(O2CCH3)(SNH2)} + O,O-Diethyl hydrogen phosphorodithioate (298-06-6) → ammonium O,O-diethyldithiophosphate (1068-22-0) + {Mo2(N(C6H4CH3))2(S2P(OC2H5)2)2S(O2CCH3)(S2PS(OC2H5)2)}

Guidance literature:

In chloroform; The Mo-compd. in CHCl3 is treated with (EtO)2PS2H and stirred 30 min.; Addn. of C6H6, centrifugation and decantation left the ammonium compd., which is further rinsed three times with C6H6, each time followed by centrifugation and decantation, and then dried.;

Reference yield:

{Mo2(N(C6H4CH3))2(S2P(OC2H5)2)2S(O2CCH3)(SNH2)} + O,O-Diethyl hydrogen phosphorodithioate (298-06-6) → bis(diethoxyphosphoryl)disulphide (2901-90-8) + ammonium O,O-diethyldithiophosphate (1068-22-0) + {Mo(NTo)(S2P(OEt)2)(μ3-S)}4

Guidance literature:

In chloroform-d1; byproducts: acetic acid; To the Mo-compd. in CDCl3 is added (EtO)2PS2H, causing rapid darkening.; Pptn. of colorless crystals; (31)P-NMR and (1)H-NMR spectroscopy;

upstream raw materials:

mixed thioanhydride of O,O-diethyl hydrogen phosphorodithioate and ethylphenylphosphinothious acid

ethanethiol

ethanol

O,O-Diethyl hydrogen phosphorodithioate

Downstream raw materials:

C₂₂H₃₄O₆P₂S₄Te

C₂₀H₃₀O₄P₂S₄Te

chlormephos

Ethion

Refernces

• 1、 -. "DITHIOPHOSPHATO-PLATINUM-COMPLEXES FOR THE TREATMENT OF CANCERS". Page/Page column 26-27. . Retrieved 2008/06/13.
• 2、 Noble, Mark E.. "A primary molybdosulfenamide". . p. 1337 - 1342. Retrieved 2008/10/08.