CID 16689079

Base Information

• Chemical Name: CID 16689079
• CAS No.: 1586-92-1
• Molecular Formula: C6H15 Al O
• Molecular Weight: 130.166
• Hs Code.: 2909199090
• Mol file: 1586-92-1.mol

Synonyms:SCHEMBL131666

Chemical Property of CID 16689079

Chemical Property:

• Vapor Pressure: 5 mm Hg ( 94 °C)
• Melting Point: 2.5-4.5oC
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 9.23000
• Density: g/cm³
• LogP: 2.43500
• Storage Temp.: 0-6°C
• Sensitive.: Air & Moisture Sensitive
• Solubility.: Soluble in hydrocarbons and ether.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 130.0938285
• Heavy Atom Count: 8
• Complexity: 13.9

Purity/Quality:

99.9% ^*data from raw suppliers

Diethylaluminum ethoxide 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): FC
• Hazard Codes: F,T,C
• Statements: 11-14-17-23/24/25-34-14/15-67-65-48/20-63
• Safety Statements: 16-26-36/37/39-45-43-27-62

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[O-].CC[Al+]CC

Technology Process of CID 16689079

There total 6 articles about CID 16689079 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

triethylaluminum (97-93-8) + sodium ethanolate (141-52-6) → diethyl(ethoxy)aluminum (1586-92-1) + sodium tetraethylaluminate (2397-68-4)

Guidance literature:

In hexane; n-heptane; toluene; at 70 ℃; for 1h;

Reference yield:

triethylaluminum (97-93-8) + aluminum ethoxide (555-75-9) → diethyl(ethoxy)aluminum (1586-92-1)

Guidance literature:

Reference yield:

hexaethyldialuminum → diethyl(ethoxy)aluminum (1586-92-1)

Guidance literature:

With O₂; In xylene; shaking of Al2Et6 soln. with different amts. of dry atm. O2 (mole ratio 3.5/1 - 2/1); spect. anal. {(27)Al-NMR};

DOI:10.1016/0022-328X(88)80228-6

upstream raw materials:

triethylaluminum

sodium ethanolate

aluminum ethoxide

Downstream raw materials:

ethyl 4-phenylbutyrate

1-methyl-4-(3-phenyl-1-propen-1-yl)benzene

tert-butyl ((2S,3S)-4-chloro-3-hydroxy-1-phenylbutan-2-yl)carbamate

nickel

Refernces

• 1、 Dzhemilev, U. M.,Kukovinets, A. G.. "MECHANISM OF LINEAR OLIGOMERIZATION OF BUTADIENE, CATALYZRD BY LOW-VALENCE COMPLEXES OF COBALT AND IRON". . . Retrieved 1983.
• 2、 -. "Process for the preparation of alkali metal tetraalkylaluminates and use thereof". Page/Page column 2. . Retrieved 2008/06/13.