1,2,2,3-Tetrachloropropane

Base Information

• Chemical Name: 1,2,2,3-Tetrachloropropane
• CAS No.: 13116-53-5
• Molecular Formula: C3H4 Cl4
• Molecular Weight: 181.877
• Hs Code.: 2903199000
• European Community (EC) Number: 236-043-9
• DSSTox Substance ID: DTXSID5051656
• Nikkaji Number: J88.018C
• Wikidata: Q81984782
• Mol file: 13116-53-5.mol

Synonyms:1,2,2,3-tetrachloropropane

Chemical Property of 1,2,2,3-Tetrachloropropane

Chemical Property:

• Vapor Pressure: 1.48mmHg at 25°C
• Melting Point: -50.2°C (estimate)
• Refractive Index: 1.4920 to 1.4950
• Boiling Point: 176.3°Cat760mmHg
• Flash Point: 62.5°C
• PSA: 0.00000
• Density: 1.471g/cm³
• LogP: 2.63790
• XLogP3: 2.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 181.903761
• Heavy Atom Count: 7
• Complexity: 44.9

Purity/Quality:

98% ^*data from raw suppliers

1,2,2,3-Tetrachloropropane >95.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(CCl)(Cl)Cl)Cl

Technology Process of 1,2,2,3-Tetrachloropropane

There total 23 articles about 1,2,2,3-Tetrachloropropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.5%

2,3-Dichloroprop-1-ene (78-88-6) → 1,2,2,3-tetrachloropropane (13116-53-5)

Guidance literature:

With chlorine; at 70 ℃; under 2250.23 Torr; Pressure; Flow reactor;

Reference yield: 19.4%

→ 1,2,2-trichloropropane (3175-23-3) + 1,1,2,2-tetrachloropropane (13116-60-4) + 1,2,3-trichloropropane (96-18-4) + 1,2,2,3-tetrachloropropane (13116-53-5) + 1,1,2,3-tetrachloropropane (18495-30-2) + 1,1,1,2,2-pentachloropropane (64240-29-5) + 1,1,1,2,3-pentachloro-propane (21700-31-2) + 1,1,2,3,3-pentachloropropane (15104-61-7) + 1,1,2,2,3-pentachloropropane (16714-68-4)

Guidance literature:

With sulfuryl dichloride; 2,2'-azobis(isobutyronitrile); at 55 - 60 ℃;

Reference yield: 15.6%

1,2-Dichloropropane (26198-63-0,78-87-5) → 1,2,2-trichloropropane (3175-23-3) + 1,1,2,2-tetrachloropropane (13116-60-4) + 1,1,2-trichloropropane (598-77-6) + 1,2,3-trichloropropane (96-18-4) + 1,2,2,3-tetrachloropropane (13116-53-5) + 1,1,2,3-tetrachloropropane (18495-30-2)

Guidance literature:

With sulfuryl dichloride; at 55 - 60 ℃;

upstream raw materials:

2,3-Dichloroprop-1-ene

1,2,2-trichloropropane

1,2,3-trichloropropane

antimonypentachloride

Downstream raw materials:

1,1,2,2,3-pentachloropropane

1,2,3-trichloropropene

1,3-dichloro-2,2-difluoropropane

1,2,3-trichloro-2-fluoro-propane

Refernces

• 1、 Hatch et al.. "-". . p. 123,126. Retrieved 1952.
• 2、 -. "Compositions comprising 2,3,3,3-tetrafluoropropene, 1,1,2,3-tetra-chloropropene, 2-chloro-3,3,3-trifluoropropene, or 2-chloro-1,1,1,2-tetrafluoropropane". Page/Page column 5. . Retrieved 2016/05/09.
• 3、 -. "SULFURYL CHLORIDE AS CHLORINATING AGENT". Paragraph 0098-00100. . Retrieved 2013/07/05.