(Chloromethyl)triphenylphosphonium iodide

Base Information

• Chemical Name: (Chloromethyl)triphenylphosphonium iodide
• CAS No.: 68089-86-1
• Molecular Formula: C19H17ClP.I
• Molecular Weight: 438.675
• European Community (EC) Number: 676-756-6
• DSSTox Substance ID: DTXSID50466379
• Mol file: 68089-86-1.mol

Synonyms:68089-86-1;(CHLOROMETHYL)TRIPHENYLPHOSPHONIUM IODIDE;chloromethyl(triphenyl)phosphanium;iodide;(Chloromethyl)triphenyl;Phosphonium, (chloromethyl)triphenyl-, iodide;Chloromethyl triphenylphosphonium iodide;COBALT(II)BROMIDEHYDRATE;SCHEMBL2446684;DTXSID50466379;YMNRWRKDEPEIAQ-UHFFFAOYSA-M;(Chloromethyl)(triphenyl)phosphanium iodide;FT-0604889;E77592;A850239

Chemical Property of (Chloromethyl)triphenylphosphonium iodide

Chemical Property:

• Melting Point: 210°C (dec.)
• Sensitive.: Light Sensitive & Hygroscopic
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 437.98011
• Heavy Atom Count: 22
• Complexity: 253

Purity/Quality:

99% ^*data from raw suppliers

(Chloromethyl)triphenylphosphonium iodide 95+% ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[P+](CCl)(C2=CC=CC=C2)C3=CC=CC=C3.[I-]

Technology Process of (Chloromethyl)triphenylphosphonium iodide

There total 2 articles about (Chloromethyl)triphenylphosphonium iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

chloromethyltriphenylphosphonium chloride (5293-84-5) → chloromethyl(triphenyl)phosphonium iodide (68089-86-1)

Guidance literature:

With methyl iodide; Heating;

Reference yield:

Chloroiodomethane (593-71-5) + triphenylphosphine (603-35-0) → chloromethyl(triphenyl)phosphonium iodide (68089-86-1)

Guidance literature:

In tert-butyl alcohol; at 83 ℃; for 6h;

DOI:10.1246/bcsj.52.1197

Reference yield: 84.6%

ethoxy(potassiosulfanyl)methanethione (35832-93-0) + chloromethyl(triphenyl)phosphonium iodide (68089-86-1) → S-(triphenylphosphonio)methyl O-ethyl thiocarbonate iodide (110637-67-7)

Guidance literature:

In chloroform; for 4h; Ambient temperature;

DOI:10.1021/jo00233a008

upstream raw materials:

Chloroiodomethane

triphenylphosphine

chloromethyltriphenylphosphonium chloride

Downstream raw materials:

Chlormethyl-triphenyl-phosphonium-tetraphenyl-borat

1-(chloromethylene)cyclohexane

Z-1-chloro-4-(2-chloroethenyl)benzene

(E)-1-(2-chlorovinyl)-4-chlorobenzene

Refernces