9-(2-HYDROXYETHYL)ANTHRACENE

Base Information

• Chemical Name: 9-(2-HYDROXYETHYL)ANTHRACENE
• CAS No.: 7512-20-1
• Molecular Formula: C₁₆H₁₄O
• Molecular Weight: 222.287
• Hs Code.: 2906299090
• Mol file: 7512-20-1.mol

Synonyms:1-(9-Anthryl)ethanol;9-(1-Hydroxyethyl)anthracene;NSC 400546;a-Methyl-9-anthracenemethanol;1-(9-Anthracenyl)ethanol;1-(Anthracen-9-yl)ethanol;

Chemical Property of 9-(2-HYDROXYETHYL)ANTHRACENE

Chemical Property:

• Appearance/Colour: Solid
• Vapor Pressure: 1.04E-07mmHg at 25°C
• Melting Point: 124-128 °C(lit.)
• Refractive Index: 1.7
• Boiling Point: 417.3 °C at 760 mmHg
• Flash Point: 186.3 °C
• PSA: 20.23000
• Density: 1.177 g/cm³
• LogP: 4.04630

Purity/Quality:

98%,99%, ^*data from raw suppliers

α-Methyl-9-anthracenemethanol 98% ^*data from reagent suppliers

Safty Information:

• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of 9-(2-HYDROXYETHYL)ANTHRACENE

There total 38 articles about 9-(2-HYDROXYETHYL)ANTHRACENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

9-acetylanthracene (784-04-3) → 9-(1-hydroxyethyl)anthracene (74928-67-9,94942-50-4,114128-93-7,7512-20-1)

Guidance literature:

With sodium tetrahydroborate; In ethanol; for 2.5h; Heating;

Reference yield: 95.0%

9-acetylanthracene (784-04-3) → (-)-(S)-1-Anthracen-9-ylethanol (7512-20-1,74928-67-9,94942-50-4,114128-93-7)

Guidance literature:

With borane-THF; Trimethylboroxine; (1R,2S)-1-Amino-2-indanol; In tetrahydrofuran; at 0 - 20 ℃;

Reference yield: 70.0%

9-(1-hydroxyethyl)anthracene (74928-67-9,94942-50-4,114128-93-7,7512-20-1) + propionic acid anhydride (123-62-6) → C19H18O2 (1312761-28-6) + (-)-(S)-1-Anthracen-9-ylethanol (7512-20-1,74928-67-9,94942-50-4,114128-93-7)

Guidance literature:

With (R)-(+)-2-phenyl-2,3-dihydrobenzo[d]imidazo[2,1-b]thiazole; N-ethyl-N,N-diisopropylamine; In chloroform; at 0 ℃; for 6h;

DOI:10.1016/j.tetasy.2011.01.019

upstream raw materials:

9-acetylanthracene

methyl magnesium iodide

9-anthracene aldehyde

methyllithium

Downstream raw materials:

anthracene

9-vinylanthracene

2-Cyclohexyl-but-3-enoic acid 1-anthracen-9-yl-ethyl ester

9-acetylanthracene

Refernces

• 1、 Du, Peng,Liu, Yan-Lan,Lu, Xiao-Bing. "P-chirogenic Trost ligands mediated asymmetric hydrogenation of simple ketones". supporting information. . Retrieved 2020/09/22.
• 2、 Neyyappadath, Rifahath Mon,Chisholm, Ross,Greenhalgh, Mark D.,Rodríguez-Escrich, Carles,Pericàs, Miquel A.,H?hner, Georg,Smith, Andrew D.. "Acylative Kinetic Resolution of Alcohols Using a Recyclable Polymer-Supported Isothiourea Catalyst in Batch and Flow". . p. 1067 - 1075. Retrieved 2018/02/14.