9-Vinylanthracene

Base Information

• Chemical Name: 9-Vinylanthracene
• CAS No.: 2444-68-0
• Molecular Formula: C16H12
• Molecular Weight: 204.271
• Hs Code.: 2902 90 00
• European Community (EC) Number: 219-486-2
• NSC Number: 91571
• UNII: A3692NGE8J
• DSSTox Substance ID: DTXSID30179197
• Nikkaji Number: J347F
• Wikidata: Q27273558
• Mol file: 2444-68-0.mol

Synonyms:9-VINYLANTHRACENE;2444-68-0;Anthracene, 9-ethenyl-;9-ethenylanthracene;MFCD00003576;9-Vinylanthracene, 97%;UNII-A3692NGE8J;A3692NGE8J;EINECS 219-486-2;NSC 91571;NSC-91571;9-vinyl-anthracene;9-Ethenyl anthracene;NSC91571;VINYLANTHRACENE, 9-;ANTHRACENE, 9-VINYL-;DTXSID30179197;BCP22510;CAA44468;AKOS005199368;AM84829;CS-W015402;SB66360;DS-16590;SY061819;FT-0621690;V0130;A817311;J-015533;J-519523;Q27273558

Chemical Property of 9-Vinylanthracene

Chemical Property:

• Appearance/Colour: yellow to green crystalline solid
• Vapor Pressure: 1.51E-05mmHg at 25°C
• Melting Point: 62-65 °C(lit.)
• Refractive Index: 1.724
• Boiling Point: 61-66 °C10 mm Hg(lit.)
• Flash Point: 172.4°C
• PSA: 0.00000
• Density: 1.112g/cm³
• LogP: 4.63600
• Storage Temp.: 2-8°C
• XLogP3: 5.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 204.093900383
• Heavy Atom Count: 16
• Complexity: 233

Purity/Quality:

98% min ^*data from raw suppliers

9-Vinylanthracene ^*data from reagent suppliers

Safty Information:

• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C=CC1=C2C=CC=CC2=CC3=CC=CC=C31
• Uses: 9-Vinylanthracene (cas# 2444-68-0) is a compound useful in organic synthesis.

Technology Process of 9-Vinylanthracene

There total 23 articles about 9-Vinylanthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

C23H23NO4 → 9-vinylanthracene (2444-68-0)

Guidance literature:

C₂₃H₂₃NO₄; at 180 - 210 ℃; under 0.01 - 0.05 Torr;

With palladium 10% on activated carbon; hydrogen; In methanol; at 20 ℃; for 24h;

DOI:10.1016/j.tetasy.2010.10.021

Reference yield: 100.0%

9-Vinyl-9,10-dihydro-anthracen-9-ol (78612-92-7) → 9-vinylanthracene (2444-68-0)

Guidance literature:

In ethanol; for 2h; Heating;

DOI:10.1055/s-1981-29437

Reference yield: 99.0%

9-(1,2-dibromoethyl)anthracene (68941-26-4) → 9-vinylanthracene (2444-68-0)

Guidance literature:

With diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; sodium carbonate; In dimethyl sulfoxide; at 20 ℃; for 1.5h; Inert atmosphere; Irradiation;

DOI:10.1002/chem.201601819

upstream raw materials:

9-anthracene aldehyde

methyl magnesium iodide

2-(anthracen-9-yl)-1,3-dithiolane

9-ethylanthracene

Downstream raw materials:

Isopropylbenzene

9-trans-styryl-anthracene

1-(9-anthryl)-ethylene oxide

9-anthracene aldehyde

Refernces

• 1、 Bigi, Franca,Camedda, Nicola,Cera, Gianpiero,Maestri, Giovanni,Maggi, Raimondo,Serafino, Andrea. "Functionalization of Alkenyl C-H Bonds with D 2 O via Pd(0)/Carboxylic Acid Catalysis". supporting information. p. 1762 - 1772. Retrieved 2020/06/08.
• 2、 Guo, Quanping,Wang, Mengran,Wang, Yanfang,Xu, Zhaoqing,Wang, Rui. "Photoinduced, copper-catalyzed three components cyanofluoroalkylation of alkenes with fluoroalkyl iodides as fluoroalkylation reagents". supporting information. p. 12317 - 12320. Retrieved 2017/11/20.