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| CAS No.: | 7486-35-3 |
|---|---|
| Name: | Tributyl(vinyl)tin |
| Molecular Structure: | |
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|
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| Formula: | C14H30Sn |
| Molecular Weight: | 317.102 |
| Synonyms: | Stannane,tributylvinyl- (8CI);Tin, tributylvinyl- (6CI);(Tributylstannyl)ethene;Ethenyltributylstannane;Tributylvinylstannane;Vinyltributyltin; |
| EINECS: | 231-291-4 |
| Density: | 1.085 g/mL at 25 °C(lit.) |
| Melting Point: | <0 °C |
| Boiling Point: | 104-106 °C (3.5 mmHg) |
| Flash Point: | 43 °C |
| Solubility: | Soluble in most organic solvents |
| Appearance: | Clear colorless to pale yellow liquid |
| Hazard Symbols: |
 T, N
|
| Risk Codes: | 21-25-36/38-48/23/25-50/53 |
| Safety: | 35-36/37/39-45-60-61 |
| Transport Information: | UN 2788 6.1/PG 3 |
| PSA: | 0.00000 |
| LogP: | 5.56070 |
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Specification
The Tributyl(vinyl)tin with CAS registry number of 7486-35-3 is also known as Vinyltributylstannane. The systematic name is Stannane, tributylvinyl-. It belongs to product categories of Monomer; Classes of Metal Compounds; Sn (Tin) Compounds; Typical Metal Compounds; Stannanes. Its EINECS registry number is 231-291-4. In addition, the formula is C14H30Sn and the molecular weight is 317.10. This chemical is a clear colorless to pale yellow liquid and should be sealed in cool, dry place. What's more, it is prepared by reaction of magnesium ethenylbromide and tributyltin chloride.
Physical properties about Tributyl(vinyl)tin are: (1)ACD/LogP: 8.87; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): 8.87; (4)ACD/LogD (pH 7.4): 8.87; (5)ACD/BCF (pH 5.5): 1000000; (6)ACD/BCF (pH 7.4): 1000000; (7)ACD/KOC (pH 5.5): 1588285.88; (8)ACD/KOC (pH 7.4): 1588285.88; (9)#Freely Rotating Bonds: 10; (10)Flash Point: 135.8 °C; (11)Enthalpy of Vaporization: 48.24 kJ/mol; (12)Boiling Point: 264.8 °C at 760 mmHg; (13)Vapour Pressure: 0.0156 mmHg at 25 °C.
Uses of Tributyl(vinyl)tin: it is used to produce allyl-benzyl ether by reaction with (chloromethoxy-methyl)-benzene. The reaction occurs with catalyst (Ph3P)4Pd and solvent benzene at the temperature of 80 °C for 4 hours. The yield is about 75%.
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When you are using this chemical, please be cautious about it. As a chemical, it is irritating to eyes and skin. It has danger of serious damage to health by prolonged exposure through inhalation and if swallowed. Besides, it is very toxic to aquatic organisms that may cause long-term adverse effects in the aquatic environment. During using it, wear suitable protective clothing, gloves and eye/face protection. This material and its container must be disposed of as hazardous waste in a safe way. Avoid release to the environment. In case of accident or if you feel unwell seek medical advice immediately.
You can still convert the following datas into molecular structure:
1. SMILES: C=C\[Sn](CCCC)(CCCC)CCCC
2. InChI: InChI=1/3C4H9.C2H3.Sn/c3*1-3-4-2;1-2;/h3*1,3-4H2,2H3;1H,2H2;/rC14H30Sn/c1-5-9-12-15(8-4,13-10-6-2)14-11-7-3/h8H,4-7,9-14H2,1-3H3
3. InChIKey: QIWRFOJWQSSRJZ-SBJYMBDBAK
4. Std. InChI: InChI=1S/3C4H9.C2H3.Sn/c3*1-3-4-2;1-2;/h3*1,3-4H2,2H3;1H,2H2;
5. Std. InChIKey: QIWRFOJWQSSRJZ-UHFFFAOYSA-N