Kinetics of decay of methyl radicals in irradiated dimethylsilanediol (cas 1066-42-8) and polymethylsiloxanes
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Add time:07/25/2019 Source:sciencedirect.com
As found by EPR spectroscopy, the decay of methyl radicals in the test compounds upon X-ray irradiation at 77 K resulted from radical-center transfer rather than radical combination; the rate constants of decay of methyl radicals in polydimethylsiloxane and its structural analog dimethylsilanediol (cas 1066-42-8) were almost the same.
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