99865-93-7

Basic information

• Product Name: methyl 2,4-dimethoxyphenylglyoxylate
• Synonyms: methyl 2,4-dimethoxyphenylglyoxylate
• CAS NO: 99865-93-7
• Molecular Weight: 224.213
• Mol File: 99865-93-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 2,4-dimethoxyphenylglyoxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,4-dimethoxyphenylglyoxylate(99865-93-7)
• EPA Substance Registry System: methyl 2,4-dimethoxyphenylglyoxylate(99865-93-7)

Safety Data

• Hazardous Substances Data: 99865-93-7(Hazardous Substances Data)

Upstream product

• 5336-27-6 2,4-dihydroxy-α-oxobenzeneacetic acid 
• 99513-27-6 (4-hydroxy-2-methoxy-phenyl)-glyoxylic acid 
• 41600-21-9 methyl 2-oxo-2-(pyrrolidin-1-yl)acetate 
• 151-10-0 1,3-Dimethoxybenzene 
• 25393-74-2 morpholin-4-yl-oxoacetic acid methyl ester 

Relevant articles and documents

Vilsmeier Formylation and Glyoxylation Reactions of Nucleophilic Aromatic Compounds Using Pyrophosphoryl Chloride

Reactions of N,N-dimethylformamide and N-methylformanilide with pyrophosphoryl chloride lead to the formation of reagents that undergo reactions with a wide range of nucleophilic aromatic substrates, including indoles, pyrroles, thiophenes, furans, and methoxy-substituted carbocyclic arenes to afford, after hydrolysis of the initial products, good to excellent yields of the expected aldehydes; reactions with methyl oxamates allow the preparation of methyl arylglyoxylates. Key words: pyrophosphoryl chloride, N,N-dimethylformamide, methoxyarene, heterocyle, formylation