99372-02-8

Basic information

• Product Name: Propanedioic acid, (1-ethenyl-1,5-dimethyl-4-hexenyl)-, diethyl ester
• CAS NO: 99372-02-8
• Molecular Formula: C17H28O4
• Molecular Weight: 296.407
• Mol File: 99372-02-8.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Propanedioic acid, (1-ethenyl-1,5-dimethyl-4-hexenyl)-, diethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Propanedioic acid, (1-ethenyl-1,5-dimethyl-4-hexenyl)-, diethyl ester(99372-02-8)
• EPA Substance Registry System: Propanedioic acid, (1-ethenyl-1,5-dimethyl-4-hexenyl)-, diethyl ester(99372-02-8)

Safety Data

• Hazardous Substances Data: 99372-02-8(Hazardous Substances Data)

Upstream product

• 106-24-1 Geraniol 
• 105-53-3 diethyl malonate 
• 61573-91-9 (E)-3,7-dimethyl-2,6-octadien-1-ylcarbonic acid ethyl ester 
• 996-82-7 sodium diethylmalonate 
• 33169-56-1 (2E,6E)-3,7-dimethyl-1-p-tolylsulfonyl-2,6-octadiene 
• 89111-67-1 triethyl geranyl ammonium iodide 
• 89111-68-2 triethyl neryl ammonium iodide 
• 87974-15-0 neryltriethylammonium bromide 
• 60699-32-3 (E)-3,7-dimethylocta-2,6-dien-1-yl diethyl phosphate 
• 105-87-3 3,7-dimethyl-2E,6-octadien-1-yl acetate 
• 141-12-8 neryl acetate 
• 72863-23-1 3,7-dimethyl-3-(p-tolylsulfonyl)-1,6-octadiene 
• 115-95-7 linalool acetate 
• 118068-95-4 C₁₄H₂₃NO₃ 

Relevant articles and documents

Et3B-promoted, Pd(0)-catalyzed allylation of active methylene compounds with allylic alcohols

Triethylborane promotes the Pd(0)-catalyzed allylation of active methylene compounds (Meldrum's acid and malonates) with a variety of allylic alcohols. The reaction proceeds smoothly at room temperature and provides the allylation products in good yield. (C) 2000 Elsevier Science Ltd.

Allylation of Active Methylene Compounds with Allyl Oxime Carbonates Catalyzed by Pd(0)

Allylation of active methylene compounds catalyzed by a palladium(0)-phosphine system took place highly stereoselectively by employing allyl oxime carbonates as the allylating reagent.

SUBSTITUTIONS CATALYSEES AU NICKEL D'ACETATES ET DE SULFONES ALLYLIQUES

The allylic substitution of stable enolates derived from diethyl malonate, ethyl cyanoacetate, ethyl benzylsulfonylacetate, bis(benzenesulfonyl)methane and sodium p-toluenesulfinate by a variety of allylic esters and sulfones has been investigated.Suitable ligands and reaction conditions have been found to ensure high yields, and in some cases considerable control of the regioselectivity of the reaction.