95448-39-8

Basic information

• Product Name: Benzene, 1-nitro-4-[S-(trifluoromethyl)sulfonimidoyl]-
• CAS NO: 95448-39-8
• Molecular Formula: C7H5F3N2O3S
• Molecular Weight: 254.19
• Mol File: 95448-39-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 1-nitro-4-[S-(trifluoromethyl)sulfonimidoyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-nitro-4-[S-(trifluoromethyl)sulfonimidoyl]-(95448-39-8)
• EPA Substance Registry System: Benzene, 1-nitro-4-[S-(trifluoromethyl)sulfonimidoyl]-(95448-39-8)

Safety Data

• Hazardous Substances Data: 95448-39-8(Hazardous Substances Data)

Upstream product

• 403-66-7 p-nitrophenyl trifluoromethyl sulfide 
• 394-60-5 1-nitro-4-[(R,S)-(trifluoromethyl)sulfinyl]benzene 
• 1111-78-0 ammonium carbamate 

Downstream Products

• 109139-29-9 N-trifluoromethylsulfonyl-S-trifluoromethyl-S-p-(4-dimethylaminophenylazo)phenylsulfoximide 
• 109139-24-4 C₈H₄F₆N₂O₅S₂ 
• 109139-25-5 N-trifluoromethylsulfonyl-S-trifluoromethyl-S-p-aminophenylsulfoximide 

Relevant articles and documents

One-Pot Synthesis of Aryl- and Alkyl S-Perfluoroalkylated NH-Sulfoximines from Sulfides

A general efficient one-pot synthesis of S-perfluoroalkylated NH-sulfoximines from sulfides has been developed using phenyliodine diacetate (PIDA) and ammonium carbamate. Remarkable rate enhancement with trifluoroethanol was observed, presumably due to H-bonding effects. These mild and metal-free conditions are compatible with -CH2F, -CFCl2, -CF2H, -CF2Br, -C4F9, and -CF3 groups, in both the alkyl- and aryl series. Based on a 19F NMR analysis, a λ6-acetoxysulfanenitrile intermediate was proposed.

S-TRIFLUOROMETHYL-S-ARYLSULFOXIMIDES

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