93189-07-2Relevant articles and documents
Transfer hydrogenation of aldehydes and ketones catalyzed using an aminophosphinite POCNHpincer complex of Ni(ii)
?ztop?u, ?zgür,Hayrapetyan, Davit,Khalimon, Andrey Y.,Lyssenko, Konstantin A.,Segizbayev, Medet,Shakhman, Dinmukhamed
, p. 11950 - 11957 (2020/09/21)
The aminophosphinite pincer complex (POCNH)NiBr was found to effectively catalyze the transfer hydrogenation of aldehydes and ketones with 2-propanol and KOtBu as a base, presenting a rare example of bifunctional nickel transfer hydrogenation catalysts. The transfer hydrogenation of aldehydes and ketones was found to be selective, tolerating a wide range of other functional groups, including those prone to reduction, such as esters, amides, alkenes, pyridines, and nitriles. The reactions were suggested to proceedviathe metal-ligand cooperative mechanism with an intermediacy of an amido (POCN)NiIIspecies.
4-amino-thieno[3,2-c] pyridine-7-carboxylic acid derivatives
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Page/Page column 39, (2010/11/26)
The present invention relates to compounds of the formula medicaments containing them and the use of these compounds as pharmaceutically active agents. The compounds exhibit activity as Raf kinase inhibitors and therefore may be useful for the treatment of diseases mediated by said kinases, especially as anticancer agents.
Method of topically treating inflammation
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, (2008/06/13)
This invention describes a method of treating inflammation in warmblooded animals by topically administering an effective amount of benzylamine and its derivatives.