91988-73-7Relevant articles and documents
Acetobromomaltose, a new source of carbohydrate radicals. EPR characterisation of maltosyl and 2-deoxymaltos-2-yl radicals and syntheses of tetrasaccharide-like mimics, maltal, 3-α-maltosyl propiononitrile, 1,5-anhydromaltitol and 2-deoxymaltopyranoside
Alberti, Angelo,Bertini, Sabrina,Comoli, Maura,Guerrini, Marco,Mele, Andrea,Vismara, Elena
, p. 6291 - 6297 (2007/10/03)
The acetoxy-protected maltosyl radical 1, obtained through bromine abstraction from acetobromomaltose (ABM), was studied by means of EPR spectroscopy. At room temperature, only the spectrum of 1 was observed, but at higher temperatures a second radical, t