91348-52-6

Basic information

• Product Name: ethyl (Z)-2-bromo-3-(4-nitrophenyl)prop-2-enoate
• Synonyms: ethyl (Z)-2-bromo-3-(4-nitrophenyl)prop-2-enoate
• CAS NO: 91348-52-6
• Molecular Weight: 300.109
• Mol File: 91348-52-6.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: ethyl (Z)-2-bromo-3-(4-nitrophenyl)prop-2-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl (Z)-2-bromo-3-(4-nitrophenyl)prop-2-enoate(91348-52-6)
• EPA Substance Registry System: ethyl (Z)-2-bromo-3-(4-nitrophenyl)prop-2-enoate(91348-52-6)

Safety Data

• Hazardous Substances Data: 91348-52-6(Hazardous Substances Data)

Upstream product

• 23755-73-9 triethyl bromophosphonoacetate 
• 555-16-8 4-nitrobenzaldehdye 
• 124755-24-4 ethyl [bis(2,2,2-trifluoroethoxy)phosphinyl]acetate 
• 803-14-5 ethyl 2-bromo-2-(triphenylphosphoranylidene)acetate 
• 599-99-5 ethyl tribromoacetate 
• 64-17-5 ethanol 
• 124520-68-9 α-bromo-4-nitro-cinnamic acid 

Downstream Products

• 42393-45-3 (Z)-2-bromo-3-(4-nitro-phenyl)-acrylic acid 
• 35283-08-0 ethyl 3-(4-nitrophenyl)prop-2-ynoate 
• 1039341-10-0 (Z)-ethyl 3-(1,3-dioxoisoindolin-2-yl)-3-(4-nitrophenyl)acrylate 

Relevant articles and documents

Preparation of α-bromoacrylates: One-pot procedure for the synthesis of conjugated acetylenic carboxylates from aldehydes with Ph3P/ Br3CCO2Et

We have established the optimal conditions for the Wittig reaction for synthesizing α-bromoacrylates with a high selectivity, and developed a simple and efficient one-pot procedure for preparing various conjugated acetylenic carboxylates in moderate to high yields. Georg Thieme Verlag Stuttgart.

Site-specific preparation of 2-carboalkoxy-4-substituted naphthalenes and 9-alkylphenanthrenes and evidence for an allene intermediate in the novel base-catalyzed cyclization of 2-alkynylbiphenyls

A site-specific preparation of 2-carboalkoxy-4-substituted naphthalenes and 9-alkylphenanthrenes is described. The successful cyclization of an allene intermediate provides supportive evidence for the previously proposed mechanism.

Microwave-assisted tandem nucleophilic substitution-Wittig reaction of α-hypervalent iodine functionalized phosphonium ylide

Under microwave irradiation conditions the tandem nucleophilic substitution-Wittig reaction of α-hypervalent iodine functionalized phosphonium ylide can occur readily to afford α-heteroatom substituted-α,β-unsaturated enoates in good yields stereo-selecti