90904-43-1

Basic information

• Product Name: Thiophene, 2,5-bis(4-methylphenyl)-3,4-diphenyl-
• CAS NO: 90904-43-1
• Molecular Formula: C30H24S
• Molecular Weight: 416.587
• Mol File: 90904-43-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Thiophene, 2,5-bis(4-methylphenyl)-3,4-diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Thiophene, 2,5-bis(4-methylphenyl)-3,4-diphenyl-(90904-43-1)
• EPA Substance Registry System: Thiophene, 2,5-bis(4-methylphenyl)-3,4-diphenyl-(90904-43-1)

Safety Data

• Hazardous Substances Data: 90904-43-1(Hazardous Substances Data)

Upstream product

• 19172-47-5 Lawessons reagent 
• 30856-48-5 2,3-diphenyl-1,4-di-p-tolylbutane-1,4-dione 
• 925913-04-8 3,4-dibromo-2,5-di(p-tolyl)thiophene 
• 98-80-6 phenylboronic acid 
• 5720-05-8 4-methylphenylboronic acid 
• 16939-13-2 3,4-diphenylthiophene 
• 106-38-7 para-bromotoluene 
• 2001-28-7 2-phenyl-1-p-tolyl-ethanone 
• 3287-02-3 4-(phenylethynyl)toluene 
• 83125-18-2 2,5-dibromo-3,4-diphenylthiophene 

Relevant articles and documents

Accessing π-expanded heterocyclics beyond dibenzothiophene: Syntheses and properties of phenanthrothiophenes

A series of phenanthrothiophenes are designed and synthesized from polyarylthiophenes through regioselective Scholl reactions in one step using iron chloride as catalyst. The molecular structures of these heteroarenes displayed multiple twisted fjords, which perturb the shapes of the polycyclic frameworks to pack in slipped to near-perfect face-to-face styles in parallel or antiparallel packings. Field-effect transistor devices using single crystals of 6,12-difluorodiphenanthro[9, 10-b:9′, 10′]thiophene gave a hole mobility of 0.22 cm2 V?1 s?1.

Silver-Catalyzed Coupling of Two Csp3-H Groups and One-Pot Synthesis of Tetrasubstituted Furans, Thiophenes, and Pyrroles

Silver-catalyzed coupling of two Csp3-H groups to form 1,4-diketones have been developed for the first time. The resultant ketones then undergo cyclization to synthesize tetrasubstituted furans, thiophenes, and pyrroles from benzyl ketone derivatives in a one-pot reaction process. This highly-efficient synthetic method, which utilizes air as the terminal oxidant and readily accessible starting materials, displays a wide substrate scope and broad functional-group tolerance.

Regioselective palladium(0)-catalyzed cross-coupling reactions and metal-halide exchange reactions of tetrabromothiophene: Optimization, scope and limitations

The Suzuki reaction of tetrabromothiophene with arylboronic acids provides a regioselective approach to various 5-aryl-2,3,4-tribromothiophenes, symmetrical 2,5-diaryl-3,4-dibromothiophenes, and tetraarylthiophenes. Unsymmetrical 2,5-diaryl-3,4-dibromo thiophenes are prepared by Suzuki reaction of 5-aryl-2,3,4-tribromothiophenes. Tetraarylthiophenes containing two different types of aryl groups are obtained by Suzuki reactions of 2,5-diaryl-3,4- dibromothiophenes. During the optimization of the conditions of each individual reaction, the solvent, the catalyst and the temperature play an important role. In several cases, classical conditions.