885669-11-4Relevant articles and documents
Synthesis method for intermolecular N-N bonding and corresponding synthesized compound
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Paragraph 0030-0032; 0033-0037; 0045-0046; 0058; 0061, (2021/07/24)
The invention relates to a synthesis method for intermolecular N-N bonding and a corresponding compound. According to the invention, the direct insertion reaction of N-H bonds by nitrene is completed, and a brand-new N-N coupling reaction method is developed. The reaction uses a nitrene precursor, under the action of a catalyst, an intermolecular direct N-N coupling reaction of the nitrene precursor and an amine compound can be realized, and a tetra-substituted hydrazine compound is constructed in one step.
Novel, efficient and regiospecific alkylation/arylation/heteroarylation of unsymmetrical azo compounds
Tsubrik, Olga,Sillard, Rannar,Maeeorg, Uno
, p. 843 - 846 (2007/10/03)
Excellent regioselectivity is observed in the addition of diverse organometallic nucleophiles to unsymmetrical azo compounds. Primary/secondary/ tertiary alkyl, aryl and heteroaryl substituents were introduced this way in high yields. Georg Thieme Verlag