88017-70-3

Basic information

• Product Name: Benzeneacetic acid, a-phenyl-, 2-propenyl ester
• CAS NO: 88017-70-3
• Molecular Formula: C17H16O2
• Molecular Weight: 252.313
• Mol File: 88017-70-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzeneacetic acid, a-phenyl-, 2-propenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneacetic acid, a-phenyl-, 2-propenyl ester(88017-70-3)
• EPA Substance Registry System: Benzeneacetic acid, a-phenyl-, 2-propenyl ester(88017-70-3)

Safety Data

• Hazardous Substances Data: 88017-70-3(Hazardous Substances Data)

Upstream product

• 1871-76-7 diphenylacetic acid chloride 
• 107-18-6 allyl alcohol 
• 117-34-0 2,2-diphenylacetic acid 
• 106-95-6 allyl bromide 
• 80735-94-0 1-Phenyl-3-buten-1-ol 
• 5831-77-6 2-allyloxypyridine 

Downstream Products

• 117-34-0 2,2-diphenylacetic acid 
• 6966-03-6 2-allyl-2,2-diphenylacetic acid 

Relevant articles and documents

Aromatic substituent effects in palladium-catalyzed intramolecular olefin oxyarylation reactions

The effect of electron-donating groups on the palladium-catalyzed intramolecular oxyarylation reaction was studied. In the case of activation at the ortho-position, the reaction favors the formation of a tricyclic lactone via C–H insertion. However, when

Palladium-catalyzed allylic esterification via C-C bond cleavage of a secondary homoallyl alcohol

Palladium-catalyzed allylic esterifications of secondary homoallyl alcohols with acids via sequential retro-allylation and esterification are demonstrated, affording the corresponding allyl ester in up to 99% yield. The electron effect of the substituent of the secondary alcohol was found to be crucial to the selective C-C bond cleavage.

Mercury(II) Oxide/Tetrafluoroboric Acid; A General Method for Esters from Carboxylic Acids and Alkyl Halides

-