85632-90-2Relevant articles and documents
Electrochemical synthesis of geminal azidonitro compounds
Ogibin,Ilovaisky,Merkulova,Nikishin
, p. 2558 - 2563 (2004)
An electrochemical method for the synthesis of geminal azidonitro compounds was developed. The method involves electrooxidative coupling of azide anions with salts of nitro compounds and affords geminal azidonitroalkanes, azidonitrocycloalkanes, and diazi
Radical-Nucleophilic (SRN1) Reactions. Part 4. Preparation, Reactions, and Electron Spin Resonance Studies of α-Nitro Azides
Al-Khalil, Suleiman I.,Bowman, W. Russell,Symons, Martyn C. R.
, p. 555 - 566 (2007/10/02)
2-Azido-2-nitropropane and 1-azido-1-nitrocyclohexane have been prepared by syntheses involving intermediate radical-anions (SRN1 and oxidative addition).SRN1 Reactions between α-nitroazides and azide, benzenesulphinate, and p-chlorobenzenethiolate proceed with loss of nitrite.The SRN1 reaction between 1-azido-1-nitrocyclohexane and the anion of 2-nitropropane proceeds with loss of azide.Reactions between 2-azido-2-nitropropane and the anions of 2-nitropropane and diethyl ethylmalonate yield oxidative dimerisation.E.s.r. spectroscopy has been used to observe electron-capture by 2-azido-2-nitropropane and its dissociation to nitrite and an ill-defined radical which may be (Me2CN3)..The addition of benzenesulphinate and the anion of 2-nitropropane to Me2C.NO2, formed by a minor dissociation route from 2C(N3)NO2>-., has been observed by e.s.r. spectroscopy.
