85478-00-8

Basic information

• Product Name: trans-[(CCH)2(tri-n-butylphosphane)2nickel(II)]
• Synonyms: trans-[(CCH)2(tri-n-butylphosphane)2nickel(II)]
• CAS NO: 85478-00-8
• Molecular Weight: 513.39
• Mol File: 85478-00-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-[(CCH)2(tri-n-butylphosphane)2nickel(II)](CAS DataBase Reference)
• NIST Chemistry Reference: trans-[(CCH)2(tri-n-butylphosphane)2nickel(II)](85478-00-8)
• EPA Substance Registry System: trans-[(CCH)2(tri-n-butylphosphane)2nickel(II)](85478-00-8)

Safety Data

• Hazardous Substances Data: 85478-00-8(Hazardous Substances Data)

Upstream product

• 19615-74-8 {NiCl₂(Tri-{n-butyl}-phosphin)2} 
• 74-86-2 acetylene 

Relevant articles and documents

Nuclear Magnetic Resonance (1H-, 13C-, 31P-, 195Pt-NMR)-Studies of Alkynyl Derivatives of Pt(II), Pd(II) and Ni(II)

The NMR parameters (1H, 13C, 31P, 195Pt) of compounds of the type cis- and trans- (M = Ni, Pd, Pt) are reported.The chemical shifts δ13C and δ195Pt (together with UV data) indicate the presence of ?-backbonding from the metal into the ?*CC orbitals.This also explaines some unusual features of the coupling constants J (13C1H), J (13C13C) and J (195Pt13C).The NMR parameters reflect an increase in the amount of ?-backbonding for Pt Pd Ni. - Keywords: Alkynyl Pt(II)-, Pd(II)-, Ni(II)-complexes, Multinuclear NMR