83766-52-3 Usage
Description
4-(Heptadecafluorooctyl)aniline is a unique organic compound characterized by the presence of a heptadecafluoroocty group attached to an aniline moiety. This structure endows the compound with distinctive properties, such as enhanced solubility in fluorous solvents and potential reactivity due to the presence of the aniline functional group. Its synthesis involves the incorporation of a highly fluorinated alkyl chain, which imparts specific characteristics that can be exploited in various chemical applications.
Uses
Used in the Synthesis of Organocatalysts:
4-(Heptadecafluorooctyl)aniline is used as a key intermediate in the synthesis of fluorous (S)-pyrrolidine-thiourea bifunctional organocatalyst. The incorporation of the heptadecafluoroocty group into the organocatalyst enhances its solubility in fluorous solvents, which is beneficial for applications in fluorous biphasic catalysis. This allows for efficient separation and recovery of the catalyst, as well as the potential for its reuse in multiple reaction cycles.
In the field of asymmetric catalysis, the use of bifunctional organocatalysts has gained significant interest due to their ability to promote a wide range of enantioselective transformations. The introduction of the 4-(heptadecafluorooctyl)aniline moiety into the organocatalyst structure can contribute to the overall performance of the catalyst, including its enantioselectivity, reactivity, and stability.
Furthermore, the unique properties of 4-(heptadecafluorooctyl)aniline may also find applications in other areas of chemistry, such as the development of new materials with specific surface properties, or as a component in the synthesis of pharmaceuticals or agrochemicals where fluorinated moieties can influence the lipophilicity, bioavailability, or metabolic stability of the final product.
Check Digit Verification of cas no
The CAS Registry Mumber 83766-52-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,3,7,6 and 6 respectively; the second part has 2 digits, 5 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 83766-52:
(7*8)+(6*3)+(5*7)+(4*6)+(3*6)+(2*5)+(1*2)=163
163 % 10 = 3
So 83766-52-3 is a valid CAS Registry Number.
InChI:InChI=1/C14H6F17N/c15-7(16,5-1-3-6(32)4-2-5)8(17,18)9(19,20)10(21,22)11(23,24)12(25,26)13(27,28)14(29,30)31/h1-4H,32H2
83766-52-3Relevant articles and documents
Highly Site-Selective Formation of Perfluoroalkylated Anilids via a Protecting Strategy by Molybdenum Hexacarbonyl Catalyst
Yuan, Chunchen,Dai, Ping,Bao, Xiaoguang,Zhao, Yingsheng
supporting information, p. 6481 - 6484 (2019/08/20)
Introducing a perfluoroalkyl group on the aromatic ring with high site selectivity remains a challenging area in organofluorine chemistry. We herein report a highly para-selective C-H perfluoroalkylation of aniline substrates using the molybdenum hexacarbonyl catalyst. Various substituted anilids derived from anilids were well-tolerated, affording the corresponding products in moderate to good yields. Preliminary mechanism studies and density functional theory calculations revealed the coordination of Mo catalyst with amides as the key factor to realize para selectivity.
Facile fabrication of multifunctional perfluoroalkyl functionalized graphene hydrogel via a synchronous reduction and grafting strategy
Li, Ting,Ding, Yunqiao,Liu, Libin,Liu, Jian,Fang, Wenyuan,Xiang, Yu,Li, Tianduo
, p. 21744 - 21753 (2015/11/10)
Fluorine-containing groups represent very promising functionalities because fluorine not only changes the physico-chemical properties of the graphene surface, it may also alter its electronic and magnetic properties. Herein, we describe, for the first tim
Synthesis and characterization of photoresponsive POSS-based polymers and their switchable water and oil wettability on cotton fabric
Huang, Jianbao,Huang, Yangen,He, Chuanglong,Gao, Yu
, p. 100339 - 100346 (2015/12/04)
Fast photoresponsive polymers containing polyhedral oligomeric silsesquioxane (POSS) and fluorinated azobenzene groups were successfully prepared via radical polymerization and characterized by NMR, FTIR, XRD, GPC, TGA, etc. The photoresponsive properties of the polymers were investigated through ultraviolet-visible absorption spectra. The trans-cis photoisomerization of the polymers in solution conformed to a first-order reaction kinetics equation. Superhydrophobicity and high oleophobicity of the cotton fabric coated with the polymer was observed when the POSS mole ratio was 3.0%. More importantly, the surface wettability of both water and oil on the coated fabrics could be intelligently controlled by applying UV irradiation in a short time.
