82992-43-6

Basic information

• Product Name: 3-Pentanone, 2-[(phenylmethoxy)methoxy]-4-(triphenylphosphoranylidene)-, (S)-
• CAS NO: 82992-43-6
• Molecular Formula: C31H31O3P
• Molecular Weight: 482.559
• Mol File: 82992-43-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Pentanone, 2-[(phenylmethoxy)methoxy]-4-(triphenylphosphoranylidene)-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Pentanone, 2-[(phenylmethoxy)methoxy]-4-(triphenylphosphoranylidene)-, (S)-(82992-43-6)
• EPA Substance Registry System: 3-Pentanone, 2-[(phenylmethoxy)methoxy]-4-(triphenylphosphoranylidene)-, (S)-(82992-43-6)

Safety Data

• Hazardous Substances Data: 82992-43-6(Hazardous Substances Data)

Upstream product

• 3587-60-8 Benzyloxymethyl chloride 
• 687-47-8 (S)-Ethyl lactate 
• 1754-88-7 ethylenetriphenylphosphorane 

Downstream Products

• 82992-47-0 (E)-(2S,3S)-2-Benzyloxymethoxy-4-methyl-hept-4-en-3-ol 
• 82992-46-9 (E)-(2S,3R)-2-Benzyloxymethoxy-4-methyl-hept-4-en-3-ol 
• 82992-44-7 (E)-(S)-2-Benzyloxymethoxy-4-methyl-hept-4-en-3-one 
• 112320-41-9 (8S,8aS)-8-hydroxy-8-methyl-6(Z)-<6'-oxo-2'(R),5'-dimethyl-7'(S)-<(benzyloxy)methoxy>-4'(E)-octenylidene>octahydroindolizidine 

Relevant articles and documents

HIGHLY STEREOCONTROLLED REDUCTION OF α'-ALKOXYENONES TO GIVE EITHER THE THREO OR ERYTHRO ALLYLIC 1,2-DIOL. ASSIGNMENT OF THE THREO CONFIGURATION TO THE C-15,C-16 DIOL OF PUMILIOTOXIN B.

Model studies indicate that the allylic diol of pumiliotoxin B has the threo configuration, and that this functionality can be prepared with excellent stereocontrol by reduction of an α'-t-butyldiphenylsilyloxyenone.