80120-40-7Relevant articles and documents
Low pressure Pd-catalyzed carbonylation in an ionic liquid using a multiphase microflow system
Rahman, Md. Taifur,Fukuyama, Takahide,Kamata, Naoya,Sato, Masaaki,Ryu, Ilhyong
, p. 2236 - 2238 (2006)
A low pressure microflow system was developed for palladium-catalyzed multiphase carbonylation reactions in an ionic liquid. The microflow system resulted in superior selectivity and higher yields in carbonylative Sonogashira coupling and amidation reactions of aryl iodides compared to the conventional batch system. The Royal Society of Chemistry 2006.
Visible-light-mediated direct access to α-ketoamides by dealkylative amidation of tertiary amines with benzoylformic acids
Zhang, Zhiguo,Liu, Fangnan,Chen, Jingwen,Zhou, Kai,Bao, Zongbi,Su, Baogen,Yang, Qiwei,Ren, Qilong,Yang, Yiwen
supporting information, (2019/10/02)
A visible-light induced direct amidation of benzoylformic acids with tertiary amines has been explored. Tertiary amines underwent N-dealkylative amidation with α-keto acid in the presence of [Ir{dFCF3ppy}2(bpy)]PF6 and Cs
Versatile Heterogeneous Palladium Catalysts for Diverse Carbonylation Reactions under Atmospheric Carbon Monoxide Pressure
Vico Solano, Marta,González Miera, Greco,Pascanu, Vlad,Inge, A. Ken,Martín-Matute, Belén
, p. 1089 - 1095 (2018/02/06)
Herein, we report a versatile carbonylation protocol using heterogeneous Pd0 nanoparticles supported on the metal–organic frameworks (MOFs) MIL-88B-NH2 (Fe/Cr). The synthesis of a vast array of carbonyls, which includes amides, esters, carboxylic acids, and α-ketoamides, was achieved through mono- and dicarbonylation reactions. The selectivity could be controlled simply by tuning the reaction conditions. Superior activity and selectivity were recorded in some cases compared to that achieved with commercial Pd/C. However, the utility of an elaborate catalyst support is questionable and important reactivity and recyclability issues are discussed.
