79399-21-6

Basic information

• Product Name: (2-methyl-4-phenylbutan-2-yl)(phenyl)sulfane
• Synonyms: (2-methyl-4-phenylbutan-2-yl)(phenyl)sulfane
• CAS NO: 79399-21-6
• Molecular Weight: 256.412
• Mol File: 79399-21-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (2-methyl-4-phenylbutan-2-yl)(phenyl)sulfane(CAS DataBase Reference)
• NIST Chemistry Reference: (2-methyl-4-phenylbutan-2-yl)(phenyl)sulfane(79399-21-6)
• EPA Substance Registry System: (2-methyl-4-phenylbutan-2-yl)(phenyl)sulfane(79399-21-6)

Safety Data

• Hazardous Substances Data: 79399-21-6(Hazardous Substances Data)

Upstream product

• 4551-15-9 phenylthiotrimethylsilane 
• 103-07-1 1,1-dimethyl-3-phenylpropyl acetate 
• 103-05-9 4-phenyl-2-methyl-2-butanol 
• 958640-39-6 trimethylsilyl ether of 2-methyl-4-phenyl-2-butanol 
• 19031-66-4 2-fluoro-2-methyl-4-phenylbutane 
• 108-98-5 thiophenol 

Downstream Products

• 4489-84-3 3-methyl-1-phenylbut-2-ene 
• 6683-51-8 2-methyl-4-phenyl-1-butene 
• 7653-94-3 1,1-dimethyl-2-phenylcyclopropane 
• 79399-23-8 phenyl(2-methyl-4-phenyl)but-2-yl sulphoxide 
• 79399-24-9 (rac)-[(2-methyl-4-phenylbutan-2-yl)sulfonyl]-benzene 
• 52017-21-7 (3-bromo-3-methyl-n-butyl)benzene 
• 79399-27-2 4-Methyl-2-phenyl-4-phenylsulfanyl-pentanoic acid methyl ester 
• 79399-29-4 3-(1,1-Dimethyl-3-phenyl-propylsulfanyl)-benzoic acid methyl ester 
• 79399-30-7 4-(1,1-Dimethyl-3-phenyl-propylsulfanyl)-benzoic acid methyl ester 
• 79399-28-3 2-(1,1-Dimethyl-3-phenyl-propylsulfanyl)-benzoic acid methyl ester 

Relevant articles and documents

Synthesis of thioethers by ini3-catalyzed substitution of siloxy group using thiosilanes

The substitution of a siloxy group using thiosilanes smoothly occurred in the presence of InI3 catalyst to yield the corresponding thioethers. InI3was a specifically effective catalyst in this reaction system, while other typical Lew

Desulfurative Chlorination of Alkyl Phenyl Sulfides

The chlorination of readily available secondary and tertiary alkyl phenyl sulfides using (dichloroiodo)benzene (PhICl2) is reported. This mild and rapid nucleophilic chlorination is extended to sulfa-Michael derived sulfides, affording elimination-sensitive β-chloro carbonyl and nitro compounds in good yields. The chlorination of enantioenriched benzylic sulfides to the corresponding inverted chlorides proceeds with high stereospecificity, thus providing a formal entry into enantioenriched chloro-Michael adducts. A mechanism implying the formation of a dichloro-λ4-sulfurane intermediate is proposed.