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772-46-3

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772-46-3 Usage

Synthesis Reference(s)

Synthetic Communications, 19, p. 293, 1989 DOI: 10.1080/00397918908050981Tetrahedron Letters, 17, p. 993, 1976

Check Digit Verification of cas no

The CAS Registry Mumber 772-46-3 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 7,7 and 2 respectively; the second part has 2 digits, 4 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 772-46:
(5*7)+(4*7)+(3*2)+(2*4)+(1*6)=83
83 % 10 = 3
So 772-46-3 is a valid CAS Registry Number.
InChI:InChI=1/C11H16O/c1-3-11(2,12)9-10-7-5-4-6-8-10/h4-8,12H,3,9H2,1-2H3

772-46-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-Methyl-1-phenyl-2-butanol

1.2 Other means of identification

Product number -
Other names 2-methyl-1-phenylbutan-2-ol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:772-46-3 SDS

772-46-3Relevant articles and documents

2,2,5,5-Tetramethyltetrahydrofuran (TMTHF): A non-polar, non-peroxide forming ether replacement for hazardous hydrocarbon solvents

Byrne, Fergal,Forier, Bart,Bossaert, Greet,Hoebers, Charly,Farmer, Thomas J.,Clark, James H.,Hunt, Andrew J.

, p. 3671 - 3678 (2017/08/15)

An inherently non-peroxide forming ether solvent, 2,2,5,5-tetramethyltetrahydrofuran (2,2,5,5-tetramethyloxolane), has been synthesized from readily available and potentially renewable feedstocks, and its solvation properties have been tested. Unlike traditional ethers, its absence of a proton at the alpha-position to the oxygen of the ether eliminates the potential to form hazardous peroxides. Additionally, this unusual structure leads to lower basicity compared with many traditional ethers, due to the concealment of the ethereal oxygen by four bulky methyl groups at the alpha-position. As such, this molecule exhibits similar solvent properties to common hydrocarbon solvents, particularly toluene. Its solvent properties have been proved by testing its performance in Fischer esterification, amidation and Grignard reactions. TMTHF's differences from traditional ethers is further demonstrated by its ability to produce high molecular weight radical-initiated polymers for use as pressure-sensitive adhesives.

Ether-directed ortho-C-H olefination with a palladium(II)/monoprotected amino acid catalyst

Li, Gang,Leow, Dasheng,Wan, Li,Yu, Jin-Quan

supporting information, p. 1245 - 1247 (2013/03/13)

Weak coordination is powerful! A PdII-catalyzed olefination of ortho-C-H bonds of arenes directed by weakly coordinating ethers is developed by using monoprotected amino acid (MPAA) ligands. This finding provides a method for chemically modifying ethers, which are abundant in natural products and drug molecules. HFIP=hexafluoroisopropanol. Copyright

Iron(II) chloride-mediated addition of dialkylmagnesium to carbonyl compounds

Sada, Mutsumi,Matsubara, Seijiro

, p. 800 - 801 (2008/12/21)

Addition reactions to carbonyl compounds with a complex reagent, prepared from organomagnesium and iron(II) chloride, were examined. The reagent works as effective nucleophile to an easily enolizable ketone such as β-tetralone; it also added to keto ester chemoselectively. Copyright

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