76280-42-7

Basic information

• Product Name: (Z)-(3,3,3-trifluoroprop-1-ene-1,2-diyl)dibenzene
• CAS NO: 76280-42-7
• Molecular Weight: 248.248
• Mol File: 76280-42-7.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: (Z)-(3,3,3-trifluoroprop-1-ene-1,2-diyl)dibenzene(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-(3,3,3-trifluoroprop-1-ene-1,2-diyl)dibenzene(76280-42-7)
• EPA Substance Registry System: (Z)-(3,3,3-trifluoroprop-1-ene-1,2-diyl)dibenzene(76280-42-7)

Safety Data

• Hazardous Substances Data: 76280-42-7(Hazardous Substances Data)

Upstream product

• 434-45-7 2,2,2-Trifluoroacetophenone 
• 329-98-6 phenylmethylsulphonyl fluoride 
• 1100-88-5 benzyltriphenylphosphonium chloride 
• 1939-99-7 benzenesulfonyl chloride 
• 136430-43-8 (Z)-(2-ethoxy-3,3,3-trifluoroprop-1-enyl)benzene 
• 591-51-5 phenyllithium 
• 136000-20-9 [(1Z)-2-(ethylthio)-3,3,3-trifluoro-1-propenyl]benzene 
• 591-50-4 iodobenzene 
• 680210-33-7 4,4,5,5-Tetramethyl-2-((E)-3,3,3-trifluoro-1,2-diphenyl-propenyl)-[1,3,2]dioxaborolane 
• 239074-65-8 1,1-dichloro-2-trifluoromethyl-4-phenylbutan-2-ol 
• 384-64-5 3,3,3-trifluoro-2-phenylpropene 
• 5123-13-7 5,5-dimethyl-2-phenyl-1,3,2-dioxaborinane 
• 98-80-6 phenylboronic acid 
• 81290-20-2 (trifluoromethyl)trimethylsilane 

Relevant articles and documents

Syntheses, structures, and thermolyses of pentacoordinate 1,2-oxastibetanes: Potential intermediates in the reactions of stibonium ylides with carbonyl compounds

Pentacoordinate 1,2-oxastibetanes 14a-d, which are formal [2 + 2]-cycloadducts of the reactions of stibonium ylides with carbonyl compounds, were successfully synthesized by the reactions of the corresponding bromo-2-hydroxyalkylstiboraiies with NaH. The

Z-trifluoromethyl thioenol ethers, enol ethers, and enamines; reactivity towards organolithium reagents

Trifluoromethyl enol ethers and thioenol ethers conjugated with an unsaturation in the β-position undergo addition/elimination reactions with organolithium reagents to yield the corresponding trifluoromethyl alkenes while preserving the geometry of the do

Synthesis of (Z)-α-Trifluoromethyl Alkenyl Triflate: A Scaffold for Diverse Trifluoromethylated Species

An efficient method for the synthesis of (Z)-selective α-trifluoromethyl alkenyl triflates is described. As an important fluorinated building block, it is utilized successfully for the synthesis of various trifluoromethyl derivatives such as diarylethylen

Pd-carbene migratory insertion: Application to the synthesis of trifluoromethylated alkenes and dienes

Pd-catalyzed cross-coupling of halides with CF3-substituted diazo compounds or N-tosylhydrazones has been explored for the synthesis of CF3-substituted alkenes and 1,3-butadienes. Pd-carbene migratory insertion plays the key role in these transformations. Copyright

One-pot multistep synthesis of trisubstituted alkenes from N -tosylhydrazones and alcohols

A one-pot procedure for the synthesis of trisubstituted alkenes from N-tosylhydrazones and alcohols is reported. This procedure combines the aerobic oxidation reaction and Wittig reaction in one pot, which avoids using of environmentally toxic oxidants and isolation of the intermediates. The simple procedure makes it very attractive for the synthesis of trisubstituted alkenes when alcohols are used as starting materials. A variety of trisubstituted alkenes as well as trifluoromethyl-substituted alkenes were obtained in moderate to good yields (up to 84%) with good E-selectivity (up to 99%). Georg Thieme Verlag Stuttgart.New York.