74728-46-4Relevant articles and documents
Preparation method of (9Z,11E)-9,11-hexadecanedional
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Paragraph 0129-0135, (2022/01/04)
The present invention provides a method for preparing (9Z,11E)-9,11-hexadecanedienal of formula (4) below, comprising: having (2E)-2-heptenoxal of formula (1) and the following general formula (2) of triarylphosphine 9,9-dialkoxynonylyelide compound under
Synthesis of E-vinyl iodides via Pd-catalyzed hydrostannation of terminal alkynes
Darwish, Alla,Chong, J. Michael
experimental part, p. 654 - 658 (2012/01/06)
E-Vinyl iodides may be prepared via a one-pot reaction involving Pd-catalyzed hydrostannation of terminal alkynes followed by iodinolysis of the intermediate vinylstannane. The synthesis is tolerant of functional groups, such as alcohols and esters.
Identification, syntheses, and characterization of the geometric isomers of 9,11-hexadecadienal from female pheromone glands of the sugar cane borer Diatraea saccharalis
Santangelo, Ellen M.,Coracini, Myrian,Witzgall, Peter,Correa, Arlene G.,Unelius, C. Rikard
, p. 909 - 915 (2007/10/03)
Chemical analysis of the pheromone glands of the sugar cane borer Diatraea saccharalis has shown the presence of the four geometric isomers of 9,11-hexadecadienal (1-4), in addition to hexadecanal and (Z)-hexadec-11-enal. We here report the syntheses and characterization of compounds 1-4, One starting material, 9-decen-1-ol, has been used to obtain all of them via divergent synthetic routes.