72445-15-9

Basic information

• Product Name: 1-Butanol, 2-methylene-4-(phenylthio)-
• CAS NO: 72445-15-9
• Molecular Formula: C11H14OS
• Molecular Weight: 194.298
• Mol File: 72445-15-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-Butanol, 2-methylene-4-(phenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Butanol, 2-methylene-4-(phenylthio)-(72445-15-9)
• EPA Substance Registry System: 1-Butanol, 2-methylene-4-(phenylthio)-(72445-15-9)

Safety Data

• Hazardous Substances Data: 72445-15-9(Hazardous Substances Data)

Upstream product

• 72445-11-5 2-Oxo-3-(2-phenylsulfanyl-ethyl)-succinic acid diethyl ester 
• 76184-45-7 3-Oxo-2-(2-phenylsulfanyl-ethyl)-butyric acid ethyl ester 
• 4837-01-8 1-bromo-2-phenylthioethane 
• 7205-91-6 phenylthiomethyl chloride 
• 72445-14-8 Ethyl-2-methylen-4-phenylthio-butanoat 
• 56137-51-0 2,2-dimethyl-5-(2-phenylsulfanyl-ethyl)-[1,3]dioxane-4,6-dione 
• 50-00-0 formaldehyd 
• 72445-13-7 2-lithio-4-phenylthiobut-1-ene 

Downstream Products

• 76184-51-5 1-(4-Hydroxymethyl-cyclohex-3-enyl)-ethanone 
• 76184-52-6 1-(3-Hydroxymethyl-cyclohex-3-enyl)-ethanone 
• 76184-48-0 (3-Chloromethyl-but-3-ene-1-sulfinyl)-benzene 
• 121783-41-3 methyl 2-methyl-4-phenylsulfonyl butanoate 
• 121783-46-8 (R)-2-Methyl-4-phenylsulfanyl-butyric acid methyl ester 
• 5392-40-5 (E/Z)-3,7-dimethyl-2,6-octadienal 
• 78791-62-5 (E)-4-Benzenesulfonyl-10,14-dimethyl-6-methylene-pentadeca-9,13-dien-2-one 
• 78791-61-4 ((E)-7,11-Dimethyl-3-methylene-dodeca-6,10-diene-1-sulfonyl)-benzene 
• 72445-08-0 ((E)-7,11-Dimethyl-3-methylene-dodeca-6,10-dienylsulfanyl)-benzene 
• 505-32-8 isophytol 
• 502-69-2 6,10,14-Trimethyl-2-pentadecanon 
• 123-35-3 7-methyl-3-methene-1,6-octadiene 
• 78791-57-8 (7-Methyl-3-methylene-oct-6-ene-1-sulfinyl)-benzene 
• 78424-79-0 (5-methyl-3-methyleneoct-6-en-1-yl)(phenyl)sulfane 

Relevant articles and documents

Direct preparation of allylstannanes from allyl alcohols: Convenient synthesis of β-substituted allylstannanes and of stereodefined γ-substituted allylstannanes

Primary allyl alcohols are converted into allyltributylstannanes in a one-pot operation. It entails (i) deprotonation with BuLi, (ii) sulfonylation with mesyl chloride, and (iii) nucleophilic substitution by LiSnBu3. Conversions are quantitative with isolated yields ranging from 70% to 100%. If the starting allyl alcohol contains a stereogenic double bond its configuration is retained.

PREPARATION AND DIELS-ALDER REACTIONS OF SOME FUNCTIONALIZED ISOPRENES

A convenient synthetic method for some functionalized isoprenes employing 1-bromo-2-phenylthioethane and ethyl acetoacetate as starting materials is reported.It has also been found that the dienes thus obtained gave functionalized limonene analogs by Diel