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68301-59-7

2'-Chloro-4'-hydroxyacetophenone is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 68301-59-7 Structure

  • Basic information

    1. Product Name: 2'-Chloro-4'-hydroxyacetophenone
    2. Synonyms: 1-(4-HYDROXY-2-CHLOROPHENYL)ETHANONE;1-(2-CHLORO-4-HYDROXY-PHENYL)-ETHANONE;2'-CHLORO-4'-HYDROXYACETOPHENONE;4'-HYDROXY-2'-CHLORO ACETOPHENONE;4-HYDROXY-2-CHLOROACETOPHENONE;1-(2-Chloro-4-hydroxyphenyl)ethan-1-one;1-(2-Chloro-4-hydroxyphenyl)ethan-1-one, 4-Acetyl-3-chlorophenol
    3. CAS NO:68301-59-7
    4. Molecular Formula: C8H7ClO2
    5. Molecular Weight: 170.59
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 68301-59-7.mol
    9. Article Data: 1

  • Chemical Properties

    1. Melting Point: 110 °C
    2. Boiling Point: 288 °C at 760 mmHg
    3. Flash Point: 128 °C
    4. Appearance: /
    5. Density: 1.298g/cm3
    6. Vapor Pressure: 0.00139mmHg at 25°C
    7. Refractive Index: 1.569
    8. Storage Temp.: N/A
    9. Solubility: N/A
    10. PKA: 7.21±0.18(Predicted)
    11. CAS DataBase Reference: 2'-Chloro-4'-hydroxyacetophenone(CAS DataBase Reference)
    12. NIST Chemistry Reference: 2'-Chloro-4'-hydroxyacetophenone(68301-59-7)
    13. EPA Substance Registry System: 2'-Chloro-4'-hydroxyacetophenone(68301-59-7)

  • Safety Data

    1. Hazard Codes: Xi
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 68301-59-7(Hazardous Substances Data)

68301-59-7 Usage

Preparation

Obtained (by-product) by Fries rearrangement of 3-chlorophenyl acetate with aluminium chloride.

Check Digit Verification of cas no

The CAS Registry Mumber 68301-59-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,8,3,0 and 1 respectively; the second part has 2 digits, 5 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 68301-59:
(7*6)+(6*8)+(5*3)+(4*0)+(3*1)+(2*5)+(1*9)=127
127 % 10 = 7
So 68301-59-7 is a valid CAS Registry Number.
InChI:InChI=1/C8H7ClO2/c1-5(10)7-3-2-6(11)4-8(7)9/h2-4,11H,1H3

68301-59-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-Chloro-4-Hydroxyacetophenone

1.2 Other means of identification

Product number -
Other names 1-(2-chloro-4-hydroxyphenyl)ethanone

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:68301-59-7 SDS

68301-59-7Relevant articles and documents

A re-investigation of the Fries rearrangement of 3-chlorophenyl acetate and synthesis of 2-azido-1-(4-(benzyloxy)-2-chlorophenyl)ethanone from 4-bromo-3-chlorophenol

Procopiou, Panayiotis A.,Coe, Diane M.,Procopiou, George

, p. 4766 - 4768 (2017/11/20)

The Fries rearrangement of 3-chlorophenyl acetate provided the expected 4-chloro-2-hydroxy-acetophenone as the major product and 2,4-diacetyl resorcinol and 2-chloro-4-hydroxy-acetophenone as minor products. 4-Benzyloxy-2-chloroacetophenone was prepared by a Heck reaction and then elaborated to 4-benzyloxy-2-chlorophenacyl azide.

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