68193-73-7

Basic information

• Product Name: tri-μ-methoxybis[(η-benzene)ruthenium(II)] tetraphenylborate
• CAS NO: 68193-73-7
• Molecular Weight: 770.704
• Mol File: 68193-73-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: tri-μ-methoxybis[(η-benzene)ruthenium(II)] tetraphenylborate(CAS DataBase Reference)
• NIST Chemistry Reference: tri-μ-methoxybis[(η-benzene)ruthenium(II)] tetraphenylborate(68193-73-7)
• EPA Substance Registry System: tri-μ-methoxybis[(η-benzene)ruthenium(II)] tetraphenylborate(68193-73-7)

Safety Data

• Hazardous Substances Data: 68193-73-7(Hazardous Substances Data)

Upstream product

• 88658-67-7 (η-benzene)chloro(trifluoroacetato)ruthenium(II) 
• 143-66-8 sodium tetraphenyl borate 
• 124-41-4 sodium methylate 
• 37366-09-9 dichloro(benzene)ruthenium(II) dimer 

Downstream Products

• 37366-09-9 dichloro(benzene)ruthenium(II) dimer 

Relevant articles and documents

SYNTHESIS AND REACTIONS OF SOME TRIPLE ALKOXO- AND THIOATO-BRIDGED ARENERUTHENIUM(II) COMPLEXES. X-RAY STRUCTURE DETERMINATION OF

Reaction of 2> (arene = C6H6, 1,4-MeC6H4CHMe2) with NaNH2 in CH3CN gives a dark oil which upon treatment with ROH/NaBPh4 (R = Me, Et) gives the triple bridged complexes (BPh4>.The structure of the benzene complex (R = Me) has been verified by X-ray analysis.The crystals are monoclinic, space group P21/n with a 11.725(4), b 15.573(5), c 18.739(2) Angstroem; β 103.29(2)deg.These complexes undergo reactions with tertiary phosphines and hydrogen halides.There is also spectroscopic evidence for intermolecular exchange of the bridging alkoxo ligands on mixing pure solutions of the + cations (M = Ru, Os).Reaction of 2> with Pb(SEt) 2 in CH3CN gives the analogous + cations.