67853-48-9

Basic information

• Product Name: (E)-4,4'-(prop-1-ene-1,3-diyl)bis(chlorobenzene)
• Synonyms: (E)-4,4'-(prop-1-ene-1,3-diyl)bis(chlorobenzene)
• CAS NO: 67853-48-9
• Molecular Weight: 263.166
• Mol File: 67853-48-9.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: (E)-4,4'-(prop-1-ene-1,3-diyl)bis(chlorobenzene)(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-4,4'-(prop-1-ene-1,3-diyl)bis(chlorobenzene)(67853-48-9)
• EPA Substance Registry System: (E)-4,4'-(prop-1-ene-1,3-diyl)bis(chlorobenzene)(67853-48-9)

Safety Data

• Hazardous Substances Data: 67853-48-9(Hazardous Substances Data)

Upstream product

• 1679-18-1 4-Chlorophenylboronic acid 
• 42432-30-4 p-chlorocinnamyl bromide 
• 13677-54-8 1,3-bis(4-chlorophenyl)prop-2-en-1-ol 
• 873-73-4 4-n-chlorophenylacetylene 
• 55-21-0 benzamide 
• 1875-88-3 2-(4-Chlorophenyl)ethanol 
• 591-87-7 Allyl acetate 
• 79185-37-8 1-(4-chlorophenyl)-3-(4-chlorophenyl)-1-propanol 

Downstream Products

• 110179-65-2 (E)-N,3-bis(4-chlorophenyl)acrylamide 
• 1352732-80-9 (E)-5-(4-chlorostyryl)-1-(4-chlorophenyl)-1H-tetrazole 
• 101385-37-9 1,3-Bis-(4-amidinophenyl)propene 
• 101340-93-6 (E)-4,4'-(prop-1-ene-1,3-diyl)dibenzonitrile 

Relevant articles and documents

Base-promoted one-pot synthesis of pyridine derivatives via aromatic alkyne annulation using benzamides as nitrogen source

In the presence of Cs2CO3, the first simple, efficient, and one-pot procedure for the synthesis of 3,5-diaryl pyridines via a variety of aromatic terminal alkynes with benzamides as the nitrogen source in sulfolane is described. The formation of pyridine derivatives accompanies the outcome of 1,3-diaryl propenes, which are also useful intermediates in organic synthesis. Thus, pyridine ring results from a formal [2+2+1+1] cyclocondensation of three alkynes with benzamides, and one of the alkynes provides one carbon, whilst benzamides provide a nitrogen source only. A new transformation of alkynes as well as new utility of benzamide are found in this work.

Manganese-Catalyzed Dual-Deoxygenative Coupling of Primary Alcohols with 2-Arylethanols

Reported herein is a general and efficient dual-deoxygenative coupling of primary alcohols with 2-arylethanols catalyzed by a well-defined Mn/PNP pincer complex. This reaction is the first example of the catalytic dual-deoxygenation of alcohols using a non-noble-metal catalyst. Both deoxygenative homocoupling of 2-arylethanols (17 examples) and their deoxygenative cross-coupling with other primary alcohols (20 examples) proceeded smoothly to form the corresponding alkenes by a dehydrogenation and deformylation reaction sequence.

Bi(OTf)3 catalyzed disproportionation reaction of cinnamyl alcohols

Bi(OTf)3 catalyzed disproportionation reaction of cinnamyl alcohols provides chalcones and benzyl styrenes. The use of various metal triflates is investigated herein for facile and efficient redox transformation. A plausible mechanism has been proposed.