67665-47-8

Basic information

• Product Name: 2,2'-DIBROMO-9,9'-SPIROBIFLUORENE
• Synonyms: DibroMo-9,9'-spirobi[9H;9,9'-Spirobi[9H-fluorene],2,2'-dibroMo-;2,2'-DIBROMO-9,9'-SPIROBIFLUORENE;2,2'-Dibromo-9,9'-spirobi[9H-fluorene]
• CAS NO: 67665-47-8
• Molecular Formula: C₂₅H₁₄Br₂
• Molecular Weight: 474.18666
• EINECS: 1312995-182-4
• Product Categories: Fluorene Derivatives
• Mol File: 67665-47-8.mol
• Article Data: 4

Chemical Properties

• Melting Point: 240°C(lit.)
• Boiling Point: 557.4 °C at 760 mmHg
• Flash Point: 335.1 °C
• Appearance: /
• Density: 1.74
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: 2,2'-DIBROMO-9,9'-SPIROBIFLUORENE(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2'-DIBROMO-9,9'-SPIROBIFLUORENE(67665-47-8)
• EPA Substance Registry System: 2,2'-DIBROMO-9,9'-SPIROBIFLUORENE(67665-47-8)

Safety Data

• Hazardous Substances Data: 67665-47-8(Hazardous Substances Data)

Usage

Chemical Properties

off-white powder

Upstream product

• 67665-45-6 2,2′-diamino-9,9′-spirobifluorene 
• 180577-88-2 4'-trimethylsilylbiphenyl-2-carboxylic acid methyl ester 
• 106-37-6 1.4-dibromobenzene 
• 17865-11-1 (4-(trimethylsilyl)phenyl)boronic acid 
• 86-73-7 9H-fluorene 
• 583-53-9 2,3-dibromobenzene 
• 98-80-6 phenylboronic acid 
• 67665-44-5 9-((1,1'-biphenyl)-2-yl)-9H-fluoren-9-ol 
• 2052-07-5 2-Bromobiphenyl 
• 486-25-9 9-fluorenone 
• 864957-73-3 bis(4'-trimethylsilanylbiphenyl-2-yl)methanone 
• 864957-74-4 bis(4'-bromobiphenyl-2-yl)methanone 
• 159-66-0 9,9'-spirobifluorene 

Downstream Products

• 864957-75-5 2,2'-dibromo-7,7'-diformyl-9,9'-spirobifluorene 
• 790674-48-5 (rac)-2,2'-diiodo-9,9'-spirobifluorene 
• 445498-73-7 2,2'-bis(5-bromo-4-hexyl-2-thienyl)-9,9'-spirobifluorene 
• 445498-74-8 C₆₅H₇₂S₄ 
• 445498-75-9 C₆₅H₇₀Br₂S₄ 

Relevant articles and documents

Synthesis and characterization of spiro-linked poly(terfluorene): A blue-emitting polymer with controlled conjugated length

The synthesis and characterization of a fluorene-spirobifluorene alternating copolymer, P(OF-SBF), are described. In the case of the spiro-segment, the two fluorene rings are orthogonally arranged and connected through a tetrahedral bonding carbon atom (t

Improved synthesis of 2,2′-Dibromo-9,9′-spirobifluorene and its 2,2′-bisdonor-7,7′-bisacceptor-substituted fluorescent derivatives

(Chemical Equation Presented) Pure 2,2′-Dibromo-9,9′- spirobifluorene was synthesized by a method that did not involve troublesome dibromination of 9,9′-spirobifluorene or Sandmeyer reaction of 2,2′-diamino-9,9′-spirobifluorene. A series of donor-acceptor orthogonally substituted 9,9′-spirobifluorene was subsequently prepared showing rich variation of fluorescence in solution and in solid state.