676-99-3Relevant articles and documents
A new microscale method for the conversion of phosphorus oxyacids to their fluorinated analogues, using cyanuric fluoride in solution and on solid support
Waerme, Rikard,Juhlin, Lars
experimental part, p. 2402 - 2408 (2011/02/26)
Cyanuric fluoride, in solution or loaded onto a Wang resin, is successfully used as a fluorinating agent for phosphorus oxy acids. The reaction is very efficient with high yields and easy workup procedures, thereby in general generating products in quantitative yields. The cyanuric fluoride is proven suitable for micromolar scale synthesis of analytical standards, particularly in its resin-bound form. Taylor & Francis Group, LLC.
New General Synthesis of Organophosphorus P-F Compounds via Reaction of Azolides of Phosphorus Acids with Acyl Fluorides: Novel Route to 2-Deoxynucleosidyl Phosphorofluoridates and Phosphorodifluoridates
Dabkowski, Wojciech,Michalski, Jan,Wasiak, Jacek,Cramer, Friedrich
, p. 817 - 820 (2007/10/02)
Tetra- and tri-coordinate P-N-imidazole derivatives and their structural analogous react smoothly with acyl fluorides to give the corresponding P-F compounds an almost quantitative yield.This method has been successfully applied to produce 2-deoxynucleosidyl phosphorofluoridates and phosphorodifluoridates.
Hydroxyphosphorane Intermediates in Substitution Reactions at Phosphorus in Acyclic Phosphonofluoridates: Evidence from Nuclear Magnetic Resonance
Granoth, Itshak,Segall, Yoffi,Waysbort, Daniel,Shirin, Ezra,Leader, Haim
, p. 4523 - 4525 (2007/10/02)
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