67592-76-1Relevant articles and documents
A new type of allylation: Synthesis of β,γ-unsaturated ketones from α-halogenated aryl ketones using an allyltributyltin(IV)-tin(II) dichloride-acetonitrile system
Yasuda, Makoto
, p. 563 - 564 (1998)
Allylation of α-halogenated aryl ketones with an allyltributyltin-tin dichloride-acetonitrile system gave β,γunsaturated ketones in high yields via selective aryl rearrangement.
Multi-product classes obtained from allylation of α-halo ketones with allylzinc bromide
Zhang, Min,Hu, Yuanyuan,Zhang, Songlin
supporting information; experimental part, p. 10732 - 10735 (2010/04/05)
An efficient, one-pot synthesis procedure for the preparation of allylic epoxides, aldehydes and homoallylic alcohols (see scheme) has been described. The three industrial products were synthesized by the reaction of allylzinc bromide with a-halo ketones